Unit 2 - Practice Quiz

CHE124 50 Questions
0 Correct 0 Wrong 50 Left
0/50

1 Which of the following equations correctly represents the relationship between the number average molecular weight of a polymer (), the molecular weight of the monomer (), and the degree of polymerization ()?

A.
B.
C.
D.

2 Which of the following polymers is classified as an inorganic polymer?

A. Polysiloxane (Silicone)
B. Polyethylene
C. Polystyrene
D. Polyvinyl chloride

3 Based on the mechanism of polymerization, Nylon 6,6 is an example of which type of polymer?

A. Addition polymer
B. Isotactic polymer
C. Condensation polymer
D. Coordination polymer

4 Which molecular structure generally results in a polymer with high density, high melting point, and high tensile strength due to efficient packing?

A. Linear structure
B. Cross-linked structure
C. Branched structure
D. Dendritic structure

5 What is the term used to describe a polymer where the substituent groups are arranged randomly along the polymer chain?

A. Eutactic
B. Isotactic
C. Atactic
D. Syndiotactic

6 How does the degree of crystallinity in a polymer affect its chemical resistance?

A. It makes the polymer water-soluble
B. Crystallinity has no effect on chemical resistance
C. Higher crystallinity increases chemical resistance
D. Higher crystallinity decreases chemical resistance

7 The temperature below which a polymer becomes hard, brittle, and glassy, and above which it becomes soft and rubbery, is known as:

A. Decomposition temperature ()
B. Glass transition temperature ()
C. Melting point ()
D. Boiling point ()

8 Which of the following factors generally decreases the Glass Transition Temperature () of a polymer?

A. Strong intermolecular forces
B. Presence of bulky side groups
C. Addition of plasticizers
D. High degree of cross-linking

9 How does the presence of bulky/rigid side groups (like phenyl in Polystyrene) affect ?

A. It causes the polymer to decompose
B. It raises by restricting chain rotation
C. It has no effect on
D. It lowers by increasing flexibility

10 Which of the following is the monomer unit for Natural Rubber?

A. Styrene
B. Butadiene
C. Isoprene (2-methyl-1,3-butadiene)
D. Chloroprene

11 The process of heating natural rubber with sulfur to improve its elasticity and strength is called:

A. Vulcanization
B. Polymerization
C. Galvanization
D. Carbonization

12 Buna-S is an elastomer formed by the copolymerization of:

A. Butadiene and Acrylonitrile
B. Isoprene and Sulphur
C. Butadiene and Styrene
D. Phenol and Formaldehyde

13 Which polymer is commonly known as Teflon and possesses high thermal stability and non-stick properties?

A. PTFE
B. PVC
C. PMMA
D. PET

14 What is the primary application of Poly(methyl methacrylate) (PMMA)?

A. Transparent substitute for glass (Plexiglass)
B. Biodegradable sutures
C. Automobile tires
D. Non-stick cookware

15 Which of the following is a condensation polymer used prominently in electrical switches and handles due to its thermosetting nature?

A. Bakelite (Phenol-Formaldehyde resin)
B. PVC
C. Nylon 6
D. Polyethylene

16 Which of the following is a biodegradable polymer?

A. Polypropylene (PP)
B. Polystyrene (PS)
C. Polylactic acid (PLA)
D. Polyvinyl chloride (PVC)

17 Polyhydroxybutyrate (PHB) belongs to which class of polymers?

A. Biopolyesters produced by bacteria
B. Synthetic conducting polymers
C. Petroleum-based elastomers
D. Inorganic polymers

18 What is the primary mechanism for the degradation of biodegradable polymers like Poly(glycolic acid) (PGA) in the body?

A. Hydrolysis
B. Thermal cracking
C. Reductive cleavage
D. Photo-oxidation

19 Which polymer is commonly used for making biodegradable surgical sutures?

A. Polyethylene terephthalate (PET)
B. Kevlar
C. Nylon 6,6
D. Poly(lactic-co-glycolic acid) (PLGA)

20 Conducting polymers primarily owe their electrical conductivity to:

A. Van der Waals forces
B. Ionic mobility in the solid state
C. Extended -electron conjugation
D. Presence of metal atoms in the backbone

21 Which was the first conducting polymer discovered, treated with iodine vapor?

A. Polyaniline
B. Polythiophene
C. Polypyrrole
D. Polyacetylene

22 The process of adding an oxidizing or reducing agent to a conjugated polymer to increase its conductivity is called:

A. Vulcanization
B. Doping
C. Curing
D. Annealing

23 In the context of conducting polymers, p-doping involves:

A. Addition of protons only
B. Breaking the polymer backbone
C. Oxidation of the polymer chain
D. Reduction of the polymer chain

24 Which charge carrier is formed when an electron is removed from a polymer chain with a non-degenerate ground state (like Polypyrrole), creating a radical-cation?

A. Soliton
B. Polaron
C. Bipolaron
D. Exciton

25 Which charge carrier is unique to polymers with a degenerate ground state (like trans-polyacetylene)?

A. Phonon
B. Soliton
C. Bipolaron
D. Polaron

26 When two polarons combine in a conducting polymer, they form a spinless dication called a:

A. Neutral Soliton
B. Soliton pair
C. Free radical
D. Bipolaron

27 How does doping affect the energy band gap of a conjugated polymer?

A. It increases the band gap significantly
B. It introduces new energy levels within the band gap, effectively reducing the energy required for conduction
C. It has no effect on the band structure
D. It removes the valence band entirely

28 Which of the following is a common application of conducting polymers?

A. Organic Light Emitting Diodes (OLEDs) and Sensors
B. High-temperature lubricants
C. Cooking utensils
D. Structural concrete reinforcement

29 What is the primary function of a lubricant?

A. To generate heat in machinery
B. To reduce friction and wear between moving surfaces
C. To increase friction between moving parts
D. To act as a fuel source

30 Which mechanism of lubrication occurs when the lubricant film is thick enough to completely separate the moving surfaces (fluid film lubrication)?

A. Thin film lubrication
B. Boundary lubrication
C. Hydrodynamic lubrication
D. Extreme pressure lubrication

31 Boundary lubrication is required when:

A. The oil film is too thin to separate surfaces completely due to high load or low speed
B. The speed is very high and load is low
C. The viscosity of the oil is extremely high
D. The oil film is thick and continuous

32 Which additives are used in lubricants to prevent metal-to-metal contact under very high loads and temperatures?

A. Anti-oxidants
B. Pour point depressants
C. Viscosity index improvers
D. Extreme Pressure (EP) additives

33 What does a high Viscosity Index (VI) indicate about a lubricating oil?

A. The oil has a low flash point
B. The viscosity changes significantly with temperature
C. The oil is very thick at room temperature
D. The viscosity changes very little with temperature

34 The lowest temperature at which an oil gives off enough vapor to ignite momentarily when a flame is brought near is called:

A. Pour point
B. Flash point
C. Cloud point
D. Fire point

35 The temperature at which a lubricating oil ceases to flow or pour is known as:

A. Flash point
B. Cloud point
C. Aniline point
D. Pour point

36 Graphite acts as a solid lubricant because:

A. It is a liquid at room temperature
B. It has a diamond-like 3D structure
C. It reacts with moisture to form oil
D. It has layered structure held by weak Van der Waals forces allowing layers to slide

37 Which chemical property of a lubricant is determined by the amount of KOH (in mg) required to neutralize the free acid in 1 gram of oil?

A. Saponification number
B. Neutralization number (Acid Value)
C. Octane number
D. Iodine value

38 Molybdenum disulfide () is an example of:

A. Emulsion
B. Solid lubricant
C. Semi-solid lubricant (Grease)
D. Liquid lubricant

39 What is the specific role of anti-oxidants as lubricant additives?

A. To prevent rust formation
B. To prevent the polymerization and decomposition of oil at high temperatures
C. To increase the viscosity
D. To lower the pour point

40 The 'Cloud Point' of a lubricant is the temperature at which:

A. The oil stops flowing
B. The oil becomes cloudy or hazy due to wax crystallization
C. The oil evaporates
D. The oil catches fire

41 In the synthesis of Silicone polymers, hydrolysis of dichlorosilane () followed by condensation yields:

A. Branched silicone polymer
B. Linear silicone polymer
C. Cross-linked silicone
D. Silica gel

42 Which of the following best describes the structure of High Density Polyethylene (HDPE)?

A. Highly branched chains, low density
B. Cross-linked network
C. Linear chains, high packing efficiency, high density
D. Alternating copolymer

43 Which of the following is NOT a factor affecting the Glass Transition Temperature ()?

A. Intermolecular forces
B. Flexibility of the chain
C. Molecular weight
D. Color of the polymer

44 Polyvinyl Chloride (PVC) is synthesized via which mechanism?

A. Cationic polymerization
B. Ring-opening polymerization
C. Free radical addition polymerization
D. Step-growth polymerization

45 What is the primary charge transport mechanism in conducting polymers?

A. Proton exchange
B. Free electron flow like metals
C. Ion diffusion
D. Hopping of charge carriers (polarons/bipolarons) between chains and along chains

46 Why are biodegradable polymers like Polycaprolactone (PCL) used in drug delivery systems?

A. They degrade slowly, releasing the drug at a controlled rate
B. They are toxic to cells
C. They are electrically conductive
D. They never degrade

47 Which lubricant property is defined as the resistance of a liquid to flow?

A. Oiliness
B. Volatility
C. Viscosity
D. Emulsification

48 Which of the following is an example of an addition polymer?

A. Bakelite
B. Terylene (Polyester)
C. Polystyrene
D. Nylon 6

49 What is the role of dopants like or in polyacetylene?

A. They cross-link the chains
B. They act as oxidizing agents (p-dopants) to withdraw electrons
C. They act as plasticizers
D. They act as reducing agents (n-dopants) to donate electrons

50 An emulsion of oil and water (semi-solid) used as a lubricant is typically known as:

A. Grease
B. Cutting fluid
C. Graphite
D. Synthetic oil