1Which of the following pairs of ions are primarily responsible for the hardness of water?
A. and
B. and
C. and
D. and
Correct Answer: and
Explanation:
Hardness in water is defined as the soap-consuming capacity of water, which is primarily caused by dissolved salts of calcium () and magnesium ().
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2Temporary hardness in water is caused by the presence of which of the following salts?
A.Bicarbonates of Calcium and Magnesium
B.Sulfates of Calcium and Magnesium
C.Nitrates of Calcium and Magnesium
D.Chlorides of Calcium and Magnesium
Correct Answer: Bicarbonates of Calcium and Magnesium
Explanation:
Temporary hardness is caused by dissolved bicarbonates of calcium () and magnesium (). It can be removed by simple boiling.
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3Which relationship correctly correlates the units of hardness?
A.1 ppm = 100 mg/L = =
B.1 mg/L = 10 ppm = =
C.1 ppm = 10 mg/L = =
D.1 ppm = 1 mg/L = =
Correct Answer: 1 ppm = 1 mg/L = =
Explanation:
The relationship between units is: .
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4Why is Calcium Carbonate () chosen as the standard for expressing hardness equivalents?
A.Its molecular weight is 100 and equivalent weight is 50, making calculations easy.
B.It is the most toxic salt found in water.
C.It is the only salt that causes hardness.
D.It is highly soluble in water.
Correct Answer: Its molecular weight is 100 and equivalent weight is 50, making calculations easy.
Explanation:
is chosen as the standard because it is the most insoluble salt that precipitates during water analysis, and its molecular weight is exactly 100 g/mol (Equivalent weight = 50), which simplifies mathematical calculations.
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5In the EDTA method for hardness determination, which indicator is used?
A.Starch
B.Eriochrome Black T (EBT)
C.Methyl Orange
D.Phenolphthalein
Correct Answer: Eriochrome Black T (EBT)
Explanation:
Eriochrome Black T (EBT) is the metal-ion indicator used in complexometric titrations with EDTA to determine water hardness.
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6What is the pH range maintained during the EDTA titration for hardness determination?
A.pH 12-13
B.pH 6-7
C.pH 9-10
D.pH 2-3
Correct Answer: pH 9-10
Explanation:
The EDTA titration requires a basic medium of pH 9-10. This is maintained using an ammoniacal buffer () to ensure the stability of the Metal-EDTA complex.
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7What is the color change observed at the end point of the EDTA titration?
A.Blue to Colorless
B.Wine Red to Blue
C.Pink to Colorless
D.Blue to Wine Red
Correct Answer: Wine Red to Blue
Explanation:
Initially, the Metal-EBT complex is wine red. At the end point, EDTA extracts the metal from the indicator (forming a colorless Metal-EDTA complex), releasing the free EBT indicator which is blue in the buffer solution ().
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8Calculate the calcium carbonate equivalent of 136 mg/L of present in a water sample. (Atomic wts: Ca=40, S=32, O=16)
A.100 mg/L
B.136 mg/L
C.68 mg/L
D.200 mg/L
Correct Answer: 100 mg/L
Explanation:
Molecular weight of .
.
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9Which of the following ions is NOT responsible for the alkalinity of water?
A.
B.
C.
D.
Correct Answer:
Explanation:
Alkalinity is caused by hydroxide (), carbonate (), and bicarbonate () ions. Chloride ions () do not contribute to alkalinity.
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10If Phenolphthalein alkalinity () is zero in a water sample, the alkalinity is due to:
A. only
B. only
C. and
D. only
Correct Answer: only
Explanation:
Phenolphthalein indicates basicity above pH 8.3. If , there are no strong bases () or carbonates (). The alkalinity is entirely due to bicarbonates (), which react only with Methyl Orange.
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11When (where is Phenolphthalein alkalinity and is Methyl Orange alkalinity), the alkalinity is caused by:
A. only
B. only
C. only
D. and
Correct Answer: only
Explanation:
When , the alkalinity is due entirely to hydroxides (). This is because hydroxides react completely during the phenolphthalein titration.
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12Which combination of ions cannot coexist in water regarding alkalinity?
A.None of the above
B. and
C. and
D. and
Correct Answer: and
Explanation:
and react with each other to form carbonate and water: . Therefore, they cannot coexist.
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13Which defect in boilers is caused by the formation of a soft, loose, and slimy precipitate?
A.Scale formation
B.Priming
C.Sludge formation
D.Caustic embrittlement
Correct Answer: Sludge formation
Explanation:
Sludge is a soft, loose, and slimy precipitate formed within the boiler, usually in colder parts. Scales are hard, adherent coatings.
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14Scales in boilers are primarily composed of:
A. and Silicates
B.
C.
D.
Correct Answer: and Silicates
Explanation:
Scales are hard deposits. Calcium sulfate () is a major cause because its solubility decreases with increasing temperature. Silicates (, ) also form very hard scales.
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15Caustic embrittlement in boilers is caused by:
A.Presence of
B.High concentration of in cracks and crevices
C.High concentration of Oxygen
D.Presence of
Correct Answer: High concentration of in cracks and crevices
Explanation:
Caustic embrittlement is a type of stress corrosion caused by the concentration of Sodium Hydroxide () in hair-line cracks and crevices of the boiler plate.
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16Which chemical is added to boiler water to prevent caustic embrittlement?
A.EDTA
B.Sodium Phosphate
C.Sodium Carbonate
D.Sodium Lignosulfonate
Correct Answer: Sodium Phosphate
Explanation:
Sodium Phosphate () is often used. However, specifically for blocking hair-line cracks to prevent caustic embrittlement, Sodium Sulfate () or Sodium Lignosulfonate is used to fill the cracks.
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17The phenomenon of producing wet steam (steam containing water droplets) is known as:
A.Corrosion
B.Scale formation
C.Foaming
D.Priming
Correct Answer: Priming
Explanation:
Priming is the carrying over of varying amounts of water droplets (boiler water) in the steam (wet steam). It is often caused by rapid boiling or high water levels.
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18Dissolved oxygen in boiler feed water causes:
A.Corrosion
B.Scale formation
C.Caustic Embrittlement
D.Priming
Correct Answer: Corrosion
Explanation:
Dissolved oxygen reacts with the boiler iron at high temperatures to form rust (), leading to pitting corrosion.
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19In the Lime-Soda process, Lime () is NOT required for the removal of:
A.Permanent calcium hardness
B.Temporary calcium hardness
C.Temporary magnesium hardness
D.Permanent magnesium hardness
Correct Answer: Permanent calcium hardness
Explanation:
Permanent calcium hardness (e.g., , ) is removed by Soda () only: . Lime is not involved.
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20Why is sodium aluminate () used in the Lime-Soda process?
A.To act as a coagulant
B.To remove dissolved gases
C.To increase the pH
D.To remove permanent hardness
Correct Answer: To act as a coagulant
Explanation:
Sodium aluminate hydrolyzes to form Aluminum Hydroxide (), which is a gelatinous precipitate that entraps fine particles and helps them settle faster (coagulation).
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21The Zeolite process (Permutit process) removes hardness by exchanging:
A. and ions with ions
B. and ions with ions
C. and ions with ions
D. ions with ions
Correct Answer: and ions with ions
Explanation:
Zeolite () exchanges its loosely held Sodium ions () for Calcium and Magnesium ions in the water, producing soft water.
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22Exhausted zeolite is regenerated using a 10% solution of:
A.
B. (Brine)
C.
D.
Correct Answer: (Brine)
Explanation:
Exhausted zeolite ( or ) is regenerated by passing a strong brine solution () through it, converting it back to Sodium Zeolite ().
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23One major disadvantage of the Zeolite process is:
A.The equipment is very bulky.
B.It requires high skilled labor.
C.The treated water contains a large amount of dissolved sodium salts.
D.It cannot produce water with zero hardness.
Correct Answer: The treated water contains a large amount of dissolved sodium salts.
Explanation:
Since Ca and Mg are exchanged for Na, the output water has a high concentration of sodium salts (, ), which can cause caustic embrittlement if used in high-pressure boilers.
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24Which process produces demineralized (deionized) water?
A.Lime-Soda process
B.Sedimentation
C.Zeolite process
D.Ion Exchange process
Correct Answer: Ion Exchange process
Explanation:
The Ion Exchange process uses both Cation and Anion exchange resins to remove all dissolved cations and anions, producing demineralized (De-ionized) water.
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25In the Ion Exchange process, the Cation exchange resin () is regenerated using:
A.Brine solution
B.Dilute
C.Dilute or
D.Distilled water
Correct Answer: Dilute or
Explanation:
The exhausted cation exchange resin () must be replenished with ions. This is done by passing a dilute acid solution through it.
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26What functional group is typically present in Anion exchange resins?
A.Hydroxyl group ()
B.Sulfonic group ()
C.Quaternary Ammonium group ()
D.Carboxylic group ()
Correct Answer: Quaternary Ammonium group ()
Explanation:
Anion exchange resins contain basic functional groups like quaternary ammonium or amino groups capable of exchanging ions.
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27Calgon conditioning prevents scale formation by forming:
A.Insoluble precipitate
B.Sludge
C.Adherent coating
D.Soluble complex compound
Correct Answer: Soluble complex compound
Explanation:
Calgon (Sodium Hexametaphosphate) reacts with calcium ions to form a soluble complex, preventing the precipitation of scale-forming salts like .
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28A water sample contains 73 mg/L of . What is its hardness in terms of equivalent? (Mol wt of )
A.146 mg/L
B.73 mg/L
C.50 mg/L
D.100 mg/L
Correct Answer: 50 mg/L
Explanation:
.
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29During the calculation of Lime requirements, the amount of Lime needed for is multiplied by:
A.1
B.2
C.0.5
D.3
Correct Answer: 2
Explanation:
requires 2 equivalents of Lime (). The first equivalent converts it to (soluble) and , and the second equivalent converts to (precipitate) and .
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30Which component does NOT require Soda () during the calculation for softening?
A.Acidity ( or )
B.Permanent Ca Hardness
C.Temporary Ca Hardness
D.Permanent Mg Hardness
Correct Answer: Temporary Ca Hardness
Explanation:
Temporary Calcium Hardness () is removed by Lime only. It does not require Soda.
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31Reverse Osmosis (RO) takes place when the applied pressure is:
A.Greater than osmotic pressure
B.Less than osmotic pressure
C.Zero
D.Equal to osmotic pressure
Correct Answer: Greater than osmotic pressure
Explanation:
To reverse the natural flow of solvent (from dilute to concentrated), a pressure greater than the osmotic pressure must be applied on the concentrated side (saline water).
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32Which semi-permeable membrane is commonly used in Reverse Osmosis?
A.Wire Mesh
B.Filter Paper
C.Muslin Cloth
D.Cellulose Acetate
Correct Answer: Cellulose Acetate
Explanation:
Cellulose Acetate or Polyamide / Polysulfone membranes are used in RO because they withstand high pressure and are semi-permeable to water but not salts.
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33Electrodialysis involves the migration of ions towards electrodes through:
A.Zeolite beds
B.Sand filters
C.Cation and Anion selective membranes
D.Charcoal layers
Correct Answer: Cation and Anion selective membranes
Explanation:
Electrodialysis uses ion-selective membranes (cation exchange membranes permit only cations; anion exchange membranes permit only anions) under an electric field to remove salts.
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34Desalination refers to the removal of:
A.Dissolved oxygen from water
B.Suspended solids from water
C.Pathogens from water
D.Dissolved salts (NaCl) from brackish or sea water
Correct Answer: Dissolved salts (NaCl) from brackish or sea water
Explanation:
Desalination is the process of removing dissolved salts, primarily sodium chloride, from brackish or sea water to make it potable.
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35The chemical formula for Bleaching Powder is:
A.
B.
C.
D.
Correct Answer:
Explanation:
Bleaching powder is Calcium oxychloride ( or ). It releases chlorine when reacted with water/acid.
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36The most effective disinfecting form of chlorine in water is:
A. gas
B. (Hypochlorous acid)
C.
D. (Hypochlorite ion)
Correct Answer: (Hypochlorous acid)
Explanation:
Hypochlorous acid () is the most potent disinfectant. It is neutral and can penetrate the cell walls of bacteria more effectively than the hypochlorite ion ().
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37What is 'Breakpoint Chlorination'?
A.The point where all bacteria are killed instantly.
B.The point where chlorine demand is satisfied and free residual chlorine begins to appear.
C.The point where chlorine gas breaks down.
D.The point where water starts boiling.
Correct Answer: The point where chlorine demand is satisfied and free residual chlorine begins to appear.
Explanation:
Breakpoint chlorination is the addition of chlorine to water until the chlorine demand (oxidation of organics/ammonia) has been satisfied, and further addition results in a linear increase in free residual chlorine.
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38Sterilization of water using Ozone () is advantageous because:
A.It leaves no harmful residue and removes color/odor.
B.It is cheaper than chlorine.
C.It increases the pH of water.
D.It has a very long residual effect.
Correct Answer: It leaves no harmful residue and removes color/odor.
Explanation:
Ozone is a powerful oxidant that breaks down to oxygen, leaving no harmful residue. It also bleaches color and removes bad taste/odor. However, it is expensive and has a short half-life.
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39According to BIS (IS 10500:2012) and WHO standards, the desirable limit for pH in drinking water is:
A.5.0 – 6.0
B.6.5 – 8.5
C.3.0 – 5.0
D.9.0 – 10.0
Correct Answer: 6.5 – 8.5
Explanation:
The standard acceptable range for pH in potable water is 6.5 to 8.5.
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40The maximum permissible limit for Total Hardness (as ) in drinking water in the absence of an alternate source is:
A.200 mg/L
B.50 mg/L
C.1000 mg/L
D.600 mg/L
Correct Answer: 600 mg/L
Explanation:
The desirable limit is 200 mg/L, but in the absence of an alternate source, the permissible limit extends to 600 mg/L.
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41Excess Fluoride in drinking water (> 1.5 mg/L) causes:
A.Kidney stones
B.Blue baby syndrome
C.Cholera
D.Fluorosis (teeth and bone decay)
Correct Answer: Fluorosis (teeth and bone decay)
Explanation:
While low levels of fluoride prevent dental caries, excess fluoride causes fluorosis, characterized by mottling of teeth and deformation of bones.
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42100 mL of water required 10 mL of 0.01M EDTA for titration. What is the total hardness?
A.10 ppm
B.500 ppm
C.1000 ppm
D.100 ppm
Correct Answer: 100 ppm
Explanation:
.
Volume of EDTA = 10 mL 10 mg .
Sample Volume = 100 mL.
.
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43Boiler corrosion due to acidity is controlled by adding:
A.Acids
B.Alkalis like or
C.Oxygen scavengers
D.Coagulants
Correct Answer: Alkalis like or
Explanation:
Acidity ( ions) attacks the boiler metal. This is neutralized by adding alkalis to maintain the pH between 8 and 9.
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44What is the function of Sodium Sulfite () or Hydrazine () in boiler feed water treatment?
A.To remove Carbon dioxide
B.To kill bacteria
C.To remove hardness
D.To remove dissolved oxygen
Correct Answer: To remove dissolved oxygen
Explanation:
These chemicals are oxygen scavengers. and .
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45Which of the following is a unit of hardness used in France?
A.ppm
B.Degree Clark ()
C.Degree French ()
D.mg/L
Correct Answer: Degree French ()
Explanation:
Degree French () is defined as 1 part of equivalent hardness per 100,000 parts of water.
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46In the determination of alkalinity, if the volume of acid used for Phenolphthalein endpoint is and total acid for Methyl Orange endpoint is , and , then:
A.Alkalinity is due to only
B.Alkalinity is due to only
C.Alkalinity is due to only
D.Impossible condition
Correct Answer: Alkalinity is due to only
Explanation:
This corresponds to (since is endpoint volume and represents total M volume). If the Phenolphthalein endpoint consumes the entire acid amount, only hydroxides were present.
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47Hard water is NOT suitable for washing clothes because:
A.It forms scum (precipitate) with soap, wasting the soap.
B.It is too hot.
C.It bleaches the clothes.
D.It contains bacteria.
Correct Answer: It forms scum (precipitate) with soap, wasting the soap.
Explanation:
Calcium and Magnesium ions react with soap (Sodium stearate) to form insoluble Calcium/Magnesium stearate (scum), which does not clean and adheres to fabrics.
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48A water sample contains . On boiling this water, the hardness:
A.Converts to temporary hardness
B.Is removed completely
C.Increases
D.Remains unchanged
Correct Answer: Remains unchanged
Explanation:
causes permanent hardness. Boiling only removes temporary hardness (bicarbonates). Therefore, the hardness due to remains unchanged.
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49Colloidal conditioning involves adding substances like kerosene, tannin, or agar-agar to:
A.Prevent scale formation by coating scale-forming precipitates
B.Reduce pH
C.Kill bacteria
D.Increase the boiling point
Correct Answer: Prevent scale formation by coating scale-forming precipitates
Explanation:
Colloidal substances get coated over the scale-forming precipitates, preventing them from adhering to each other or the boiler walls, keeping them as loose sludge.
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50In the standard EDTA solution preparation, why is Magnesium added to the EDTA solution sometimes?
A.To act as a catalyst
B.To sharpen the end point if the sample has no Mg
C.To increase pH
D.To precipitate Calcium
Correct Answer: To sharpen the end point if the sample has no Mg
Explanation:
The Mg-EBT complex is more stable than Ca-EBT but less stable than Mg-EDTA. A sharp color change requires the breakdown of the Mg-EBT complex. If a sample has only Ca, Mg is added to the titrant (as Mg-EDTA) to ensure a sharp endpoint.