Unit 5: Corrosion - Practice Quiz

CHE124 — Engineering Chemistry 60 Questions
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1 Corrosion is best defined as the:

Definition and scope of corrosion Easy
A. Melting of metals at high temperatures during processing
B. Coating of metals with a protective layer of paint
C. Physical deformation of metals under applied mechanical load
D. Gradual destruction of metals by chemical or electrochemical reaction with their environment

2 The reddish-brown deposit formed when iron corrodes in moist air is commonly called:

Definition and scope of corrosion Easy
A. Rust
B. Scale
C. Slag
D. Patina

3 Corrosion generally occurs because most metals in nature tend to:

Definition and scope of corrosion Easy
A. Return to their more stable combined (compound) form
B. Convert completely into pure gases
C. Increase in mechanical strength over time
D. Stay permanently in their pure metallic state

4 Direct chemical corrosion is also known as:

direct chemical corrosion Easy
A. Pitting corrosion
B. Galvanic corrosion
C. Wet corrosion
D. Dry corrosion

5 Which of the following is an example of direct chemical (dry) corrosion?

direct chemical corrosion Easy
A. Oxidation of a metal surface by dry oxygen at high temperature
B. Corrosion at the water line of a steel tank
C. Rusting of iron in the presence of moist air and dissolved oxygen
D. Corrosion of a pipe partly buried in wet soil

6 In dry oxidation corrosion, a protective oxide film is one that is:

direct chemical corrosion Easy
A. Stable, tightly adhering, and non-porous
B. Liquid and flows away from the surface
C. Loose, porous, and easily flaked off
D. Volatile and escapes as a gas

7 Electrochemical corrosion requires the presence of:

Electrochemical corrosion and different mechanisms Easy
A. Ultraviolet light
B. High mechanical stress
C. Only dry gases
D. A conducting liquid or electrolyte

8 During electrochemical corrosion, oxidation of the metal takes place at the:

Electrochemical corrosion and different mechanisms Easy
A. Air-water interface only
B. Electrolyte surface
C. Cathodic region
D. Anodic region

9 In the oxygen absorption mechanism of electrochemical corrosion, which ion is formed at the cathode?

Electrochemical corrosion and different mechanisms Easy
A. Hydroxide ion,
B. Hydrogen ion,
C. Chloride ion,
D. Sulphate ion,

10 The hydrogen evolution mechanism of electrochemical corrosion generally occurs in:

Electrochemical corrosion and different mechanisms Easy
A. Strongly alkaline environments
B. Oil-based environments
C. Acidic environments
D. Completely dry environments

11 Galvanic corrosion occurs when:

Types of electrochemical corrosion-Galvanic and concentration cells Easy
A. A metal is painted with an inert coating
B. A metal is kept in a completely dry room
C. Two dissimilar metals are in electrical contact in an electrolyte
D. A single pure metal is heated in dry air

12 When zinc and copper are connected together in an electrolyte, which metal corrodes preferentially?

Types of electrochemical corrosion-Galvanic and concentration cells Easy
A. Both equally
B. Neither metal corrodes
C. Zinc
D. Copper

13 A concentration cell corrosion arises due to differences in the:

Types of electrochemical corrosion-Galvanic and concentration cells Easy
A. Melting points of two joined metals
B. Colour of the metal surface
C. Thickness of applied paint only
D. Concentration of electrolyte or oxygen at different parts of the metal

14 In differential aeration corrosion, the region exposed to a lower oxygen concentration behaves as the:

Types of electrochemical corrosion-Differential aeration corrosion Easy
A. Anode and corrodes
B. Insulator
C. Cathode and is protected
D. Electrolyte

15 Differential aeration corrosion is caused mainly by differences in the amount of:

Types of electrochemical corrosion-Differential aeration corrosion Easy
A. Applied electrical voltage
B. Sunlight on the metal surface
C. Carbon in the metal alloy
D. Oxygen reaching different parts of the metal surface

16 In a steel tank partly filled with water, water-line corrosion occurs:

Water-line corrosion and Pitting corrosion Easy
A. Just below the water line
B. At the very bottom of the tank
C. Above the water line in dry air
D. Uniformly over the whole tank

17 Pitting corrosion is characterized by:

Water-line corrosion and Pitting corrosion Easy
A. A protective shiny film covering the metal
B. Bending of the metal without any material loss
C. Uniform thinning across the entire surface
D. Formation of small, localized holes or pits on the metal surface

18 Intergranular corrosion takes place mainly:

Types of electrochemical corrosion-Intergranular and Soil corrosion and Factors affecting corrosion Easy
A. In the surrounding electrolyte, not the metal
B. On the painted outer surface only
C. Only at the exact centre of each grain
D. Along the grain boundaries of the metal

19 Which factor generally increases the rate of corrosion of a metal?

Types of electrochemical corrosion-Intergranular and Soil corrosion and Factors affecting corrosion Easy
A. Higher humidity and presence of moisture
B. A perfectly non-porous protective oxide layer
C. Completely dry surroundings
D. A highly nobler position in the electrochemical series

20 In cathodic protection using a sacrificial anode, the metal to be protected is connected to a metal that is:

Protection of corrosion Easy
A. A non-metallic insulator
B. More active (more easily oxidized) than the protected metal
C. Identical in every property to the protected metal
D. Less active than the protected metal

21 Rusting of iron in a moist environment is best classified as which type of process, considering that it involves loss of metal to its surroundings?

Definition and scope of corrosion Medium
A. A purely physical wearing away of metal by friction
B. A beneficial process that strengthens the metal lattice
C. A reversible physical adsorption of moisture on the metal surface
D. A destructive attack of metal by chemical or electrochemical reaction with its environment

22 Corrosion is often described as the reverse of extraction metallurgy. What does this statement imply thermodynamically?

Definition and scope of corrosion Medium
A. Metals tend to revert to their lower-energy combined (ore-like) state
B. Metals gain free energy while corroding
C. Corrosion requires external energy input to proceed
D. Pure metals are more stable than their compounds

23 According to the Pilling–Bedworth rule, a metal forms a protective oxide layer when the ratio of oxide volume to metal volume is:

direct chemical corrosion Medium
A. Greater than or equal to 1 but not excessively high
B. Always less than 1
C. Exactly equal to 0
D. Greater than 3 in all cases

24 Alkali metals like Na and K, and alkaline earth metals like Mg, form porous non-protective oxide films. This is because their Pilling–Bedworth ratio is:

direct chemical corrosion Medium
A. Between 2 and 3
B. Greater than 5
C. Less than 1
D. Equal to 1

25 Which of the following gases is responsible for the formation of a metal chloride during direct chemical (dry) corrosion of a metal at high temperature?

direct chemical corrosion Medium
A. vapour
B.
C.
D.

26 In the hydrogen evolution mechanism of electrochemical corrosion, what reaction occurs at the cathode in an acidic medium?

Electrochemical corrosion and different mechanisms Medium
A.
B.
C.
D.

27 In the oxygen absorption mechanism of corrosion in a neutral aerated solution, the cathodic reaction produces:

Electrochemical corrosion and different mechanisms Medium
A. gas
B. ions
C. ions
D. ions

28 During electrochemical corrosion, where does the actual loss (dissolution) of metal always occur?

Electrochemical corrosion and different mechanisms Medium
A. Only at the electrolyte surface
B. At the anodic region
C. At the cathodic region
D. Uniformly over both regions

29 When zinc and copper are electrically coupled and exposed to an electrolyte, which metal corrodes and why?

Types of electrochemical corrosion-Galvanic and concentration cells Medium
A. Neither, because coupling stops corrosion
B. Copper, because it is more anodic
C. Both corrode equally
D. Zinc, because it is more anodic (less noble)

30 A steel bolt used to join two copper plates in a marine structure corrodes rapidly. The main reason is:

Types of electrochemical corrosion-Galvanic and concentration cells Medium
A. The large anodic steel area is coupled to small cathodic copper
B. The small anodic steel area is coupled to a large cathodic copper area
C. Steel is more noble than copper
D. Copper acts as the sacrificial anode

31 In a concentration cell formed by a single metal dipped in electrolyte of two different metal-ion concentrations, corrosion occurs at the electrode in contact with:

Types of electrochemical corrosion-Galvanic and concentration cells Medium
A. Both equally
B. Neither electrode
C. The concentrated (higher ion concentration) solution
D. The dilute (lower ion concentration) solution

32 In differential aeration corrosion, which region of the metal surface becomes anodic?

Types of electrochemical corrosion-Differential aeration corrosion Medium
A. The region exposed to lower oxygen concentration
B. The region exposed to higher oxygen concentration
C. The region with maximum surface area
D. The region at the highest temperature

33 A metal partly immersed in water and partly exposed to air corrodes most severely just below the waterline. This is because:

Types of electrochemical corrosion-Differential aeration corrosion Medium
A. The waterline region is fully passivated
B. Oxygen is absent throughout the metal
C. The air-exposed part acts as the anode
D. The submerged, less aerated part acts as the anode

34 In pitting corrosion, once a small pit forms under a dirt or scale deposit, why does corrosion accelerate within the pit?

Water-line corrosion and Pitting corrosion Medium
A. The pit becomes oxygen-poor and acts as a small anode against a large cathode
B. The pit becomes oxygen-rich and turns cathodic
C. The pit spreads uniformly to reduce intensity
D. The deposit supplies extra oxygen to the pit

35 Water-line corrosion is commonly observed in steel water storage tanks. The line of attack forms because:

Water-line corrosion and Pitting corrosion Medium
A. The metal above the water is fully submerged
B. Water above the line is less aerated and becomes anodic
C. There is no oxygen concentration difference
D. Water below the line is less aerated and becomes anodic

36 Intergranular corrosion in welded stainless steel (weld decay) occurs mainly because:

Types of electrochemical corrosion-Intergranular and Soil corrosion and Factors affecting corrosion Medium
A. Iron carbide forms at the grain centres
B. The grains grow larger and become anodic
C. Chromium carbide precipitates at grain boundaries, depleting chromium there
D. Excess chromium accumulates at grain boundaries

37 Which factor generally increases the rate of soil corrosion of buried metal pipelines?

Types of electrochemical corrosion-Intergranular and Soil corrosion and Factors affecting corrosion Medium
A. Complete absence of dissolved ions
B. High soil moisture and dissolved salt content
C. Very dry, sandy, high-resistivity soil
D. Highly alkaline soil forming passive films

38 In the sacrificial anode method of cathodic protection for a buried iron pipeline, a suitable anode metal is:

Protection of corrosion Medium
A. Magnesium
B. Nickel
C. Silver
D. Copper

39 Galvanising protects iron even if the zinc coating is scratched, whereas tinning fails at a scratch. This difference arises because:

Protection of corrosion Medium
A. Both coatings are anodic to iron
B. Tin is anodic to iron, but zinc is cathodic to iron
C. Zinc is anodic to iron, but tin is cathodic to iron
D. Both coatings are cathodic to iron

40 Ceramic coatings are widely used to protect metals in high-temperature environments mainly because they:

Protection of corrosion-Ceramic coating Medium
A. React readily with oxygen to form new metals
B. Melt easily to seal cracks continuously
C. Are electrically conductive and act as sacrificial anodes
D. Are chemically inert and withstand high temperatures

41 A metal spontaneously reverts to its combined (oxide) state during corrosion. From a thermodynamic standpoint, why is corrosion of most engineering metals a spontaneous process?

Definition and scope of corrosion Hard
A. Metals corrode only because atmospheric oxygen forces a non-spontaneous reaction
B. Corrosion is driven purely by kinetics with at all temperatures
C. The free energy of the metallic state is lower than the oxidized state, giving
D. The free energy of the metallic state is higher than that of its ore-like oxidized state, giving for oxidation

42 The Pilling–Bedworth ratio (PBR) predicts protective behavior of oxide films. For a metal whose oxide has , what corrosion behavior is expected?

direct chemical corrosion Hard
A. No oxide forms at all since
B. Highly protective, continuous film that stops further oxidation
C. Non-protective, porous film because the oxide volume is insufficient to cover the metal surface
D. Protective film that cracks only above

43 In high-temperature oxidation following a parabolic rate law, the weight gain relates to time as . If the oxide layer thickness after 1 hour is , what is it after 4 hours (assuming ideal parabolic kinetics)?

direct chemical corrosion Hard
A.
B.
C.
D.

44 During electrochemical corrosion of iron in a neutral aerated solution, the anodic reaction is . What is the corresponding cathodic reaction that consumes the liberated electrons?

Electrochemical corrosion and different mechanisms Hard
A. (hydrogen evolution)
B. (metal deposition)
C. (oxygen absorption)
D. (oxygen evolution)

45 In acidic, oxygen-free (deaerated) media, corrosion of iron proceeds by which mechanism, and what characteristic evidence appears at the cathodic sites?

Electrochemical corrosion and different mechanisms Hard
A. Oxygen absorption mechanism; accumulates at cathodic areas
B. Direct chemical attack; a dry oxide scale forms uniformly
C. Differential aeration; rust rings form at the metal edges
D. Hydrogen evolution mechanism; gas bubbles form at cathodic areas

46 Two dissimilar metals are coupled in an electrolyte. In a Zn–Cu galvanic couple and an Fe–Sn couple (tin coating on iron), which combination protects the base metal and which accelerates its corrosion when the coating is scratched?

Types of electrochemical corrosion-Galvanic and concentration cells Hard
A. Both Zn and Sn coatings sacrificially protect the underlying metal equally
B. Zn accelerates corrosion of the coupled metal, while Sn protects iron even when scratched
C. Zn protects Cu-side steel by sacrificing itself, while scratched tin accelerates iron corrosion
D. Neither couple shows preferential attack since both are galvanic

47 A concentration cell forms when identical copper electrodes are placed in solutions of and . Which electrode acts as the anode?

Types of electrochemical corrosion-Galvanic and concentration cells Hard
A. Both dissolve equally as the potentials cancel
B. The electrode in the concentrated () solution
C. Neither, since identical metals cannot form a cell
D. The electrode in the dilute () solution

48 In differential aeration corrosion, which region of the metal becomes anodic and undergoes attack?

Types of electrochemical corrosion-Differential aeration corrosion Hard
A. Both regions corrode at equal rates
B. The region exposed to lower oxygen concentration
C. The region exposed to higher oxygen concentration
D. The region with the thickest oxide film

49 A steel bolt fastens two plates, leaving a tight crevice. Why does crevice corrosion, driven by differential aeration, tend to be autocatalytic and self-accelerating?

Types of electrochemical corrosion-Differential aeration corrosion Hard
A. Hydroxide accumulation inside the crevice passivates the anode over time
B. Oxygen concentration inside the crevice rises steadily, boosting cathodic reduction there
C. The crevice interior becomes cathodic, so the surrounding metal corrodes uniformly
D. Metal-ion buildup inside the crevice draws in and lowers local pH, further attacking the anode

50 In a partially filled steel water tank, corrosion is most severe just below the waterline. What is the correct explanation based on differential aeration?

Water-line corrosion and Pitting corrosion Hard
A. Corrosion is uniform since the whole tank contacts the same water
B. The area below the waterline is poorly aerated and anodic, while the well-aerated surface layer is cathodic
C. The area above the waterline is anodic due to atmospheric oxygen
D. The waterline itself corrodes because it has the highest oxygen concentration

51 Pitting corrosion is considered more dangerous than uniform corrosion despite low overall metal loss. What is the primary reason?

Water-line corrosion and Pitting corrosion Hard
A. Pits form only on the surface and never deepen
B. Localized deep pits penetrate rapidly and can perforate a component before significant weight loss is detected
C. Pitting always spreads to cover the entire surface uniformly
D. Pitting increases the total weight of the metal, masking damage

52 A dust particle sits on a stainless steel surface exposed to a chloride solution, initiating a pit. Why does the area covered by the particle become anodic?

Water-line corrosion and Pitting corrosion Hard
A. Oxygen access is blocked under the particle, creating an oxygen-deficient anodic zone by differential aeration
B. The particle physically scratches away the metal to expose the anode
C. The particle increases oxygen concentration locally, making that area anodic
D. The particle raises local pH, forcing cathodic behavior around it

53 Intergranular corrosion (weld decay) in austenitic stainless steel arises from sensitization. What microstructural change makes the grain-boundary regions anodic?

Types of electrochemical corrosion-Intergranular and Soil corrosion Hard
A. Carbon migrates to grain centers, leaving boundaries carbon-rich and passive
B. Chromium carbide precipitates at grain boundaries, depleting adjacent zones of chromium below the passivation limit
C. Grain boundaries gain excess chromium, becoming strongly cathodic
D. Iron carbide precipitates within grains, enriching boundaries with chromium

54 Which practical measure does NOT effectively prevent intergranular (weld decay) corrosion in stainless steel?

Types of electrochemical corrosion-Intergranular and Soil corrosion Hard
A. Solution heat treatment (quenching) to redissolve chromium carbides
B. Using low-carbon grades such as 304L or 316L
C. Adding stabilizing elements like Ti or Nb to form stable carbides
D. Cold-working the steel after welding to increase dislocation density

55 A buried steel pipeline runs through alternating sandy and clay soils. Why is the section in clay more likely to become anodic and corrode?

Types of electrochemical corrosion-Intergranular and Soil corrosion Hard
A. Soil type has no bearing; corrosion depends only on pipe metallurgy
B. Clay is denser and less aerated, so that section is oxygen-starved and anodic relative to the well-aerated sandy section
C. Clay holds more oxygen, making the pipe there strongly cathodic
D. Sandy soil retains water and increases anodic dissolution in that zone

56 Regarding the effect of the anode-to-cathode area ratio on corrosion rate, which condition produces the most rapid, dangerous localized attack?

Types of electrochemical corrosion-Intergranular and Soil corrosion and Factors affecting corrosion Hard
A. No relation exists between area ratio and corrosion rate
B. Equal anode and cathode areas, giving uniform low current density
C. Small anode coupled to a large cathode, concentrating a high current density on the small anode
D. Large anode coupled to a small cathode, spreading current over a wide area

57 In impressed current cathodic protection (ICCP) of a buried steel tank, the structure is connected to the negative terminal of a DC source with an inert anode. How does this differ fundamentally from sacrificial anode protection?

Protection of corrosion Hard
A. ICCP uses an external power source and inert/semi-inert anodes, while sacrificial protection relies on a more active metal being consumed
B. Both methods make the protected metal anodic to suppress cathodic reactions
C. ICCP requires a more noble metal anode that is never consumed at all
D. ICCP consumes the steel structure, while sacrificial protection uses an external power source

58 Anodic (passivation) inhibitors such as chromates and phosphates are described as "dangerous" inhibitors. Why can insufficient dosing be worse than adding none?

Protection of corrosion Hard
A. Underdosing raises the pH so high that the metal dissolves as a complex
B. They accelerate hydrogen evolution over the entire surface at any dose
C. Incomplete surface coverage leaves small unprotected anodes with a large cathode, causing intense localized pitting
D. Low doses convert the whole surface into a uniform cathode, stopping all corrosion

59 Ceramic coatings (e.g., oxides, carbides, nitrides) protect metals in aggressive high-temperature environments. Which property mismatch is the most critical failure risk to control when applying a ceramic coating on a metal substrate?

Protection of corrosion-Ceramic coating Hard
A. The high electrical conductivity of the ceramic, which promotes galvanic coupling
B. The low melting point of ceramics compared to the metal substrate
C. A large difference in thermal expansion coefficients, which causes cracking or spalling during thermal cycling
D. The ductility of ceramics being higher than that of the metal

60 In an electroplating operation, a current of is passed for seconds through a copper sulphate bath. Using Faraday's laws (, atomic mass , ), what mass of copper is deposited?

Electroplating process Hard
A.
B.
C.
D.