A.Melting of metals at high temperatures during processing
B.Physical deformation of metals under applied mechanical load
C.Coating of metals with a protective layer of paint
D.Gradual destruction of metals by chemical or electrochemical reaction with their environment
Correct Answer: Gradual destruction of metals by chemical or electrochemical reaction with their environment
Explanation:
Corrosion is the deterioration and loss of metal due to chemical or electrochemical reaction with its surroundings, converting the metal into more stable compounds like oxides.
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2The reddish-brown deposit formed when iron corrodes in moist air is commonly called:
Definition and scope of corrosion
Easy
A.Scale
B.Rust
C.Patina
D.Slag
Correct Answer: Rust
Explanation:
Rust is hydrated iron(III) oxide, , formed when iron corrodes in the presence of moisture and oxygen.
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3Corrosion generally occurs because most metals in nature tend to:
Definition and scope of corrosion
Easy
A.Increase in mechanical strength over time
B.Return to their more stable combined (compound) form
C.Convert completely into pure gases
D.Stay permanently in their pure metallic state
Correct Answer: Return to their more stable combined (compound) form
Explanation:
Metals are extracted from ores by supplying energy, so pure metals are in a high-energy state and tend to revert to their stable combined (oxide, sulphide) form through corrosion.
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4Direct chemical corrosion is also known as:
direct chemical corrosion
Easy
A.Pitting corrosion
B.Dry corrosion
C.Wet corrosion
D.Galvanic corrosion
Correct Answer: Dry corrosion
Explanation:
Direct chemical corrosion occurs by direct attack of gases or liquids on the metal surface in the absence of moisture, so it is called dry corrosion.
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5Which of the following is an example of direct chemical (dry) corrosion?
direct chemical corrosion
Easy
A.Rusting of iron in the presence of moist air and dissolved oxygen
B.Oxidation of a metal surface by dry oxygen at high temperature
C.Corrosion of a pipe partly buried in wet soil
D.Corrosion at the water line of a steel tank
Correct Answer: Oxidation of a metal surface by dry oxygen at high temperature
Explanation:
Dry corrosion involves direct reaction of gases such as dry oxygen with the metal without any electrolyte. The other examples all involve moisture and are electrochemical (wet) corrosion.
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6In dry oxidation corrosion, a protective oxide film is one that is:
direct chemical corrosion
Easy
A.Loose, porous, and easily flaked off
B.Volatile and escapes as a gas
C.Stable, tightly adhering, and non-porous
D.Liquid and flows away from the surface
Correct Answer: Stable, tightly adhering, and non-porous
Explanation:
A protective oxide layer must be non-porous and adhere firmly to the metal so it blocks further contact between metal and oxygen, stopping additional corrosion.
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7Electrochemical corrosion requires the presence of:
Electrochemical corrosion and different mechanisms
Easy
A.Ultraviolet light
B.A conducting liquid or electrolyte
C.High mechanical stress
D.Only dry gases
Correct Answer: A conducting liquid or electrolyte
Explanation:
Electrochemical (wet) corrosion occurs when a metal is in contact with an electrolyte such as moisture or salt solution, allowing ion and electron flow between anodic and cathodic areas.
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8During electrochemical corrosion, oxidation of the metal takes place at the:
Electrochemical corrosion and different mechanisms
Easy
A.Air-water interface only
B.Cathodic region
C.Electrolyte surface
D.Anodic region
Correct Answer: Anodic region
Explanation:
At the anode the metal loses electrons and dissolves as ions (oxidation): . Reduction reactions occur at the cathode.
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9In the oxygen absorption mechanism of electrochemical corrosion, which ion is formed at the cathode?
Electrochemical corrosion and different mechanisms
Easy
A.Hydrogen ion,
B.Hydroxide ion,
C.Sulphate ion,
D.Chloride ion,
Correct Answer: Hydroxide ion,
Explanation:
In a neutral or slightly alkaline medium, oxygen is reduced at the cathode: , forming hydroxide ions.
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10The hydrogen evolution mechanism of electrochemical corrosion generally occurs in:
Electrochemical corrosion and different mechanisms
Easy
A.Completely dry environments
B.Strongly alkaline environments
C.Oil-based environments
D.Acidic environments
Correct Answer: Acidic environments
Explanation:
In acidic media, hydrogen ions are reduced at the cathode to release hydrogen gas: , which is the hydrogen evolution mechanism.
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11Galvanic corrosion occurs when:
Types of electrochemical corrosion-Galvanic and concentration cells
Easy
A.A single pure metal is heated in dry air
B.Two dissimilar metals are in electrical contact in an electrolyte
C.A metal is painted with an inert coating
D.A metal is kept in a completely dry room
Correct Answer: Two dissimilar metals are in electrical contact in an electrolyte
Explanation:
In galvanic corrosion two dissimilar metals connected in an electrolyte form a cell; the more active (anodic) metal corrodes faster while the nobler metal is protected.
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12When zinc and copper are connected together in an electrolyte, which metal corrodes preferentially?
Types of electrochemical corrosion-Galvanic and concentration cells
Easy
A.Zinc
B.Both equally
C.Copper
D.Neither metal corrodes
Correct Answer: Zinc
Explanation:
Zinc is more active (higher in the electrochemical series) than copper, so it acts as the anode and corrodes, while copper acts as the cathode and is protected.
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13A concentration cell corrosion arises due to differences in the:
Types of electrochemical corrosion-Galvanic and concentration cells
Easy
A.Melting points of two joined metals
B.Thickness of applied paint only
C.Concentration of electrolyte or oxygen at different parts of the metal
D.Colour of the metal surface
Correct Answer: Concentration of electrolyte or oxygen at different parts of the metal
Explanation:
Concentration cells form when the same metal is exposed to different concentrations of electrolyte or oxygen, creating anodic and cathodic areas that drive corrosion.
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14In differential aeration corrosion, the region exposed to a lower oxygen concentration behaves as the:
Types of electrochemical corrosion-Differential aeration corrosion
Easy
A.Insulator
B.Cathode and is protected
C.Anode and corrodes
D.Electrolyte
Correct Answer: Anode and corrodes
Explanation:
The poorly oxygenated area becomes anodic and undergoes corrosion, while the well-aerated area acts as the cathode and remains protected.
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15Differential aeration corrosion is caused mainly by differences in the amount of:
Types of electrochemical corrosion-Differential aeration corrosion
Easy
A.Oxygen reaching different parts of the metal surface
B.Carbon in the metal alloy
C.Sunlight on the metal surface
D.Applied electrical voltage
Correct Answer: Oxygen reaching different parts of the metal surface
Explanation:
Unequal supply of oxygen over the metal surface sets up a difference in potential, making the oxygen-poor region anodic and causing localized corrosion.
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16In a steel tank partly filled with water, water-line corrosion occurs:
Water-line corrosion and Pitting corrosion
Easy
A.At the very bottom of the tank
B.Just below the water line
C.Above the water line in dry air
D.Uniformly over the whole tank
Correct Answer: Just below the water line
Explanation:
The area just above the water line is well aerated (cathode) and the area just below is poorly aerated (anode), so corrosion concentrates just below the water line.
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17Pitting corrosion is characterized by:
Water-line corrosion and Pitting corrosion
Easy
A.Formation of small, localized holes or pits on the metal surface
B.Bending of the metal without any material loss
C.A protective shiny film covering the metal
D.Uniform thinning across the entire surface
Correct Answer: Formation of small, localized holes or pits on the metal surface
Explanation:
Pitting corrosion is a highly localized attack that produces small cavities or pits, often starting where a protective film breaks down, such as under a dust particle.
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18Intergranular corrosion takes place mainly:
Types of electrochemical corrosion-Intergranular and Soil corrosion and Factors affecting corrosion
Easy
A.Only at the exact centre of each grain
B.Along the grain boundaries of the metal
C.On the painted outer surface only
D.In the surrounding electrolyte, not the metal
Correct Answer: Along the grain boundaries of the metal
Explanation:
Intergranular corrosion occurs preferentially at grain boundaries, which are often chemically different and more reactive than the grain interiors.
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19Which factor generally increases the rate of corrosion of a metal?
Types of electrochemical corrosion-Intergranular and Soil corrosion and Factors affecting corrosion
Easy
A.A perfectly non-porous protective oxide layer
B.Completely dry surroundings
C.Higher humidity and presence of moisture
D.A highly nobler position in the electrochemical series
Correct Answer: Higher humidity and presence of moisture
Explanation:
Moisture acts as an electrolyte and speeds up electrochemical corrosion; the more active a metal and the more humid the environment, the faster it corrodes.
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20In cathodic protection using a sacrificial anode, the metal to be protected is connected to a metal that is:
Protection of corrosion
Easy
A.Identical in every property to the protected metal
B.Less active than the protected metal
C.A non-metallic insulator
D.More active (more easily oxidized) than the protected metal
Correct Answer: More active (more easily oxidized) than the protected metal
Explanation:
A more active metal such as zinc or magnesium acts as the sacrificial anode and corrodes in place of the structure, making the protected metal the cathode.
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21Rusting of iron in a moist environment is best classified as which type of process, considering that it involves loss of metal to its surroundings?
Definition and scope of corrosion
Medium
A.A purely physical wearing away of metal by friction
B.A reversible physical adsorption of moisture on the metal surface
C.A beneficial process that strengthens the metal lattice
D.A destructive attack of metal by chemical or electrochemical reaction with its environment
Correct Answer: A destructive attack of metal by chemical or electrochemical reaction with its environment
Explanation:
Corrosion is defined as the destruction or deterioration of a metal by chemical or electrochemical reaction with its environment, converting the metal into stable compounds like oxides.
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22Corrosion is often described as the reverse of extraction metallurgy. What does this statement imply thermodynamically?
Definition and scope of corrosion
Medium
A.Metals gain free energy while corroding
B.Pure metals are more stable than their compounds
C.Metals tend to revert to their lower-energy combined (ore-like) state
D.Corrosion requires external energy input to proceed
Correct Answer: Metals tend to revert to their lower-energy combined (ore-like) state
Explanation:
Extraction converts stable ores into high-energy pure metals. Corrosion is the spontaneous reverse, where metals return to their thermodynamically stable, lower-energy combined forms.
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23According to the Pilling–Bedworth rule, a metal forms a protective oxide layer when the ratio of oxide volume to metal volume is:
direct chemical corrosion
Medium
A.Greater than 3 in all cases
B.Always less than 1
C.Greater than or equal to 1 but not excessively high
D.Exactly equal to 0
Correct Answer: Greater than or equal to 1 but not excessively high
Explanation:
If the specific volume ratio of oxide to metal is , the oxide layer is non-porous and protective. If it is less than 1, the layer is porous and non-protective.
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24Alkali metals like Na and K, and alkaline earth metals like Mg, form porous non-protective oxide films. This is because their Pilling–Bedworth ratio is:
direct chemical corrosion
Medium
A.Less than 1
B.Greater than 5
C.Between 2 and 3
D.Equal to 1
Correct Answer: Less than 1
Explanation:
For these metals the oxide volume is smaller than the metal volume (), so the film cannot cover the surface completely, remains porous, and allows continued oxidation.
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25Which of the following gases is responsible for the formation of a metal chloride during direct chemical (dry) corrosion of a metal at high temperature?
direct chemical corrosion
Medium
A.
B. vapour
C.
D.
Correct Answer:
Explanation:
In dry corrosion by gases, chlorine reacts directly with the metal to form volatile metal chlorides. Gases like , , and attack metals chemically without an electrolyte.
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26In the hydrogen evolution mechanism of electrochemical corrosion, what reaction occurs at the cathode in an acidic medium?
Electrochemical corrosion and different mechanisms
Medium
A.
B.
C.
D.
Correct Answer:
Explanation:
In acidic, oxygen-free environments, cathodic reaction reduces hydrogen ions to hydrogen gas. The anodic reaction is metal dissolution, e.g. .
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27In the oxygen absorption mechanism of corrosion in a neutral aerated solution, the cathodic reaction produces:
Electrochemical corrosion and different mechanisms
Medium
A. gas
B. ions
C. ions
D. ions
Correct Answer: ions
Explanation:
In neutral/alkaline aerated conditions the cathodic reaction is , generating hydroxide ions that combine with metal ions to form rust.
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28During electrochemical corrosion, where does the actual loss (dissolution) of metal always occur?
Electrochemical corrosion and different mechanisms
Medium
A.Uniformly over both regions
B.At the cathodic region
C.Only at the electrolyte surface
D.At the anodic region
Correct Answer: At the anodic region
Explanation:
Oxidation (metal dissolution) occurs at the anode, so corrosion damage is localised there, while reduction reactions occur at the cathode where the metal is protected.
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29When zinc and copper are electrically coupled and exposed to an electrolyte, which metal corrodes and why?
Types of electrochemical corrosion-Galvanic and concentration cells
Medium
A.Copper, because it is more anodic
B.Neither, because coupling stops corrosion
C.Zinc, because it is more anodic (less noble)
D.Both corrode equally
Correct Answer: Zinc, because it is more anodic (less noble)
Explanation:
In a galvanic couple the more active metal (higher in the activity series) becomes the anode. Zinc is more anodic than copper, so zinc corrodes and copper is protected.
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30A steel bolt used to join two copper plates in a marine structure corrodes rapidly. The main reason is:
Types of electrochemical corrosion-Galvanic and concentration cells
Medium
A.The small anodic steel area is coupled to a large cathodic copper area
B.Steel is more noble than copper
C.Copper acts as the sacrificial anode
D.The large anodic steel area is coupled to small cathodic copper
Correct Answer: The small anodic steel area is coupled to a large cathodic copper area
Explanation:
A small anode–large cathode ratio concentrates the corrosion current on the small steel anode, causing intense localised corrosion of the bolt.
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31In a concentration cell formed by a single metal dipped in electrolyte of two different metal-ion concentrations, corrosion occurs at the electrode in contact with:
Types of electrochemical corrosion-Galvanic and concentration cells
Medium
A.The dilute (lower ion concentration) solution
B.The concentrated (higher ion concentration) solution
C.Both equally
D.Neither electrode
Correct Answer: The dilute (lower ion concentration) solution
Explanation:
The electrode in the more dilute electrolyte acts as the anode (its potential is lower), so metal dissolves there while the electrode in concentrated solution is cathodic.
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32In differential aeration corrosion, which region of the metal surface becomes anodic?
Types of electrochemical corrosion-Differential aeration corrosion
Medium
A.The region at the highest temperature
B.The region exposed to higher oxygen concentration
C.The region exposed to lower oxygen concentration
D.The region with maximum surface area
Correct Answer: The region exposed to lower oxygen concentration
Explanation:
The poorly aerated (oxygen-deficient) area becomes anodic and corrodes, while the well-aerated area becomes cathodic. This oxygen difference drives the corrosion current.
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33A metal partly immersed in water and partly exposed to air corrodes most severely just below the waterline. This is because:
Types of electrochemical corrosion-Differential aeration corrosion
Medium
A.The submerged, less aerated part acts as the anode
B.The air-exposed part acts as the anode
C.The waterline region is fully passivated
D.Oxygen is absent throughout the metal
Correct Answer: The submerged, less aerated part acts as the anode
Explanation:
The submerged region receives less oxygen and becomes anodic, so corrosion concentrates just below the waterline where aeration difference is greatest.
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34In pitting corrosion, once a small pit forms under a dirt or scale deposit, why does corrosion accelerate within the pit?
Water-line corrosion and Pitting corrosion
Medium
A.The deposit supplies extra oxygen to the pit
B.The pit spreads uniformly to reduce intensity
C.The pit becomes oxygen-rich and turns cathodic
D.The pit becomes oxygen-poor and acts as a small anode against a large cathode
Correct Answer: The pit becomes oxygen-poor and acts as a small anode against a large cathode
Explanation:
The oxygen-shielded pit bottom stays anodic while the surrounding aerated surface is a large cathode. This small anode–large cathode geometry drives rapid, deep penetration.
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35Water-line corrosion is commonly observed in steel water storage tanks. The line of attack forms because:
Water-line corrosion and Pitting corrosion
Medium
A.There is no oxygen concentration difference
B.Water above the line is less aerated and becomes anodic
C.Water below the line is less aerated and becomes anodic
D.The metal above the water is fully submerged
Correct Answer: Water below the line is less aerated and becomes anodic
Explanation:
Dissolved oxygen is higher near the surface. The area just below the waterline is oxygen-deficient, becomes anodic, and corrodes as a distinct line.
Types of electrochemical corrosion-Intergranular and Soil corrosion and Factors affecting corrosion
Medium
A.Excess chromium accumulates at grain boundaries
B.Iron carbide forms at the grain centres
C.The grains grow larger and become anodic
D.Chromium carbide precipitates at grain boundaries, depleting chromium there
Correct Answer: Chromium carbide precipitates at grain boundaries, depleting chromium there
Explanation:
Heating causes to precipitate at grain boundaries, leaving adjacent zones chromium-depleted and anodic, so corrosion attacks the boundaries preferentially.
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37Which factor generally increases the rate of soil corrosion of buried metal pipelines?
Types of electrochemical corrosion-Intergranular and Soil corrosion and Factors affecting corrosion
Medium
A.Highly alkaline soil forming passive films
B.High soil moisture and dissolved salt content
C.Complete absence of dissolved ions
D.Very dry, sandy, high-resistivity soil
Correct Answer: High soil moisture and dissolved salt content
Explanation:
Moist, salt-rich soil has low electrical resistivity and acts as a good electrolyte, accelerating electrochemical corrosion of buried metal.
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38In the sacrificial anode method of cathodic protection for a buried iron pipeline, a suitable anode metal is:
Protection of corrosion
Medium
A.Magnesium
B.Nickel
C.Silver
D.Copper
Correct Answer: Magnesium
Explanation:
The sacrificial anode must be more active than iron. Magnesium (also Zn, Al) is more anodic, so it corrodes preferentially and protects the iron structure.
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39Galvanising protects iron even if the zinc coating is scratched, whereas tinning fails at a scratch. This difference arises because:
Protection of corrosion
Medium
A.Zinc is anodic to iron, but tin is cathodic to iron
B.Both coatings are cathodic to iron
C.Both coatings are anodic to iron
D.Tin is anodic to iron, but zinc is cathodic to iron
Correct Answer: Zinc is anodic to iron, but tin is cathodic to iron
Explanation:
Zinc sacrifices itself to protect exposed iron. Tin is nobler than iron, so at a scratch iron becomes the small anode and corrodes rapidly.
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40Ceramic coatings are widely used to protect metals in high-temperature environments mainly because they:
Protection of corrosion-Ceramic coating
Medium
A.React readily with oxygen to form new metals
B.Are electrically conductive and act as sacrificial anodes
C.Melt easily to seal cracks continuously
D.Are chemically inert and withstand high temperatures
Correct Answer: Are chemically inert and withstand high temperatures
Explanation:
Ceramic coatings (oxides, carbides, nitrides) are chemically stable, thermally resistant, and provide a hard inert barrier, making them ideal for high-temperature corrosion protection.
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41A metal spontaneously reverts to its combined (oxide) state during corrosion. From a thermodynamic standpoint, why is corrosion of most engineering metals a spontaneous process?
Definition and scope of corrosion
Hard
A.The free energy of the metallic state is lower than the oxidized state, giving
B.Corrosion is driven purely by kinetics with at all temperatures
C.Metals corrode only because atmospheric oxygen forces a non-spontaneous reaction
D.The free energy of the metallic state is higher than that of its ore-like oxidized state, giving for oxidation
Correct Answer: The free energy of the metallic state is higher than that of its ore-like oxidized state, giving for oxidation
Explanation:
Metals are extracted from ores by supplying energy, so the refined metal is in a high-energy metastable state. Reverting to the oxidized (ore-like) state lowers free energy (), making corrosion thermodynamically spontaneous.
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42The Pilling–Bedworth ratio (PBR) predicts protective behavior of oxide films. For a metal whose oxide has , what corrosion behavior is expected?
direct chemical corrosion
Hard
A.No oxide forms at all since
B.Protective film that cracks only above
C.Non-protective, porous film because the oxide volume is insufficient to cover the metal surface
D.Highly protective, continuous film that stops further oxidation
Correct Answer: Non-protective, porous film because the oxide volume is insufficient to cover the metal surface
Explanation:
When , the oxide volume is less than the metal consumed, so the film is porous and cannot fully cover the surface, allowing continued oxidation. Protective films typically have .
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43In high-temperature oxidation following a parabolic rate law, the weight gain relates to time as . If the oxide layer thickness after 1 hour is , what is it after 4 hours (assuming ideal parabolic kinetics)?
direct chemical corrosion
Hard
A.
B.
C.
D.
Correct Answer:
Explanation:
Parabolic law: . At h, . The film thickens more slowly over time as it becomes protective.
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44During electrochemical corrosion of iron in a neutral aerated solution, the anodic reaction is . What is the corresponding cathodic reaction that consumes the liberated electrons?
Electrochemical corrosion and different mechanisms
Hard
A. (hydrogen evolution)
B. (oxygen evolution)
C. (oxygen absorption)
D. (metal deposition)
Correct Answer: (oxygen absorption)
Explanation:
In neutral or slightly basic aerated media, hydrogen ion concentration is very low, so corrosion proceeds by oxygen absorption. Dissolved oxygen is reduced at the cathode to form hydroxide ions.
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45In acidic, oxygen-free (deaerated) media, corrosion of iron proceeds by which mechanism, and what characteristic evidence appears at the cathodic sites?
Electrochemical corrosion and different mechanisms
Hard
A.Hydrogen evolution mechanism; gas bubbles form at cathodic areas
B.Differential aeration; rust rings form at the metal edges
C.Direct chemical attack; a dry oxide scale forms uniformly
D.Oxygen absorption mechanism; accumulates at cathodic areas
Correct Answer: Hydrogen evolution mechanism; gas bubbles form at cathodic areas
Explanation:
In acidic deaerated solutions, ions are reduced to gas at the cathode (). The visible hydrogen bubbles distinguish this from the oxygen-absorption route.
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46Two dissimilar metals are coupled in an electrolyte. In a Zn–Cu galvanic couple and an Fe–Sn couple (tin coating on iron), which combination protects the base metal and which accelerates its corrosion when the coating is scratched?
Types of electrochemical corrosion-Galvanic and concentration cells
Hard
A.Neither couple shows preferential attack since both are galvanic
B.Zn accelerates corrosion of the coupled metal, while Sn protects iron even when scratched
C.Both Zn and Sn coatings sacrificially protect the underlying metal equally
D.Zn protects Cu-side steel by sacrificing itself, while scratched tin accelerates iron corrosion
Correct Answer: Zn protects Cu-side steel by sacrificing itself, while scratched tin accelerates iron corrosion
Explanation:
Zinc is anodic to iron (galvanizing = sacrificial protection). Tin is cathodic to iron; once the tin layer is scratched, the exposed iron becomes a small anode coupled to a large tin cathode, so iron corrodes rapidly.
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47A concentration cell forms when identical copper electrodes are placed in solutions of and . Which electrode acts as the anode?
Types of electrochemical corrosion-Galvanic and concentration cells
Hard
A.The electrode in the concentrated () solution
B.Both dissolve equally as the potentials cancel
C.Neither, since identical metals cannot form a cell
D.The electrode in the dilute () solution
Correct Answer: The electrode in the dilute () solution
Explanation:
In a metal-ion concentration cell, the electrode in the more dilute solution has the more negative potential and dissolves (anode) to raise its ion concentration, while metal deposits at the concentrated electrode (cathode).
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48In differential aeration corrosion, which region of the metal becomes anodic and undergoes attack?
Types of electrochemical corrosion-Differential aeration corrosion
Hard
A.The region with the thickest oxide film
B.The region exposed to higher oxygen concentration
C.The region exposed to lower oxygen concentration
D.Both regions corrode at equal rates
Correct Answer: The region exposed to lower oxygen concentration
Explanation:
The poorly oxygenated area becomes the anode and corrodes, while the well-aerated area acts as the cathode (where is reduced). This is the basis of waterline and crevice corrosion.
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49A steel bolt fastens two plates, leaving a tight crevice. Why does crevice corrosion, driven by differential aeration, tend to be autocatalytic and self-accelerating?
Types of electrochemical corrosion-Differential aeration corrosion
Hard
A.Oxygen concentration inside the crevice rises steadily, boosting cathodic reduction there
B.Hydroxide accumulation inside the crevice passivates the anode over time
C.Metal-ion buildup inside the crevice draws in and lowers local pH, further attacking the anode
D.The crevice interior becomes cathodic, so the surrounding metal corrodes uniformly
Correct Answer: Metal-ion buildup inside the crevice draws in and lowers local pH, further attacking the anode
Explanation:
Inside the oxygen-starved crevice (anode), accumulates; charge balance draws in , and metal-ion hydrolysis lowers pH. The increasingly acidic, chloride-rich pocket intensifies attack, making it autocatalytic.
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50In a partially filled steel water tank, corrosion is most severe just below the waterline. What is the correct explanation based on differential aeration?
Water-line corrosion and Pitting corrosion
Hard
A.The area below the waterline is poorly aerated and anodic, while the well-aerated surface layer is cathodic
B.Corrosion is uniform since the whole tank contacts the same water
C.The area above the waterline is anodic due to atmospheric oxygen
D.The waterline itself corrodes because it has the highest oxygen concentration
Correct Answer: The area below the waterline is poorly aerated and anodic, while the well-aerated surface layer is cathodic
Explanation:
Water near the surface is oxygen-rich (cathodic); the region just below the waterline is oxygen-poor and becomes anodic. This differential aeration cell produces the characteristic band of attack below the waterline.
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51Pitting corrosion is considered more dangerous than uniform corrosion despite low overall metal loss. What is the primary reason?
Water-line corrosion and Pitting corrosion
Hard
A.Pitting always spreads to cover the entire surface uniformly
B.Pits form only on the surface and never deepen
C.Pitting increases the total weight of the metal, masking damage
D.Localized deep pits penetrate rapidly and can perforate a component before significant weight loss is detected
Correct Answer: Localized deep pits penetrate rapidly and can perforate a component before significant weight loss is detected
Explanation:
Pitting concentrates attack at tiny anodic sites (often under a scratch or deposit). The small anode-to-large cathode ratio drives deep, fast penetration that can cause sudden failure while overall weight loss remains negligible.
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52A dust particle sits on a stainless steel surface exposed to a chloride solution, initiating a pit. Why does the area covered by the particle become anodic?
Water-line corrosion and Pitting corrosion
Hard
A.The particle increases oxygen concentration locally, making that area anodic
B.The particle raises local pH, forcing cathodic behavior around it
C.Oxygen access is blocked under the particle, creating an oxygen-deficient anodic zone by differential aeration
D.The particle physically scratches away the metal to expose the anode
Correct Answer: Oxygen access is blocked under the particle, creating an oxygen-deficient anodic zone by differential aeration
Explanation:
The metal beneath the deposit is shielded from oxygen and becomes anodic relative to the surrounding aerated surface. Pit initiation follows, aided by chloride ingress that breaks down the passive film.
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53Intergranular corrosion (weld decay) in austenitic stainless steel arises from sensitization. What microstructural change makes the grain-boundary regions anodic?
Types of electrochemical corrosion-Intergranular and Soil corrosion
Hard
A.Grain boundaries gain excess chromium, becoming strongly cathodic
B.Chromium carbide precipitates at grain boundaries, depleting adjacent zones of chromium below the passivation limit
C.Carbon migrates to grain centers, leaving boundaries carbon-rich and passive
D.Iron carbide precipitates within grains, enriching boundaries with chromium
Correct Answer: Chromium carbide precipitates at grain boundaries, depleting adjacent zones of chromium below the passivation limit
Explanation:
Heating (e.g., welding) at – precipitates at grain boundaries. The neighboring chromium-depleted zones fall below the ~12% Cr needed for passivity and corrode preferentially as anodes.
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54Which practical measure does NOT effectively prevent intergranular (weld decay) corrosion in stainless steel?
Types of electrochemical corrosion-Intergranular and Soil corrosion
Hard
A.Cold-working the steel after welding to increase dislocation density
B.Solution heat treatment (quenching) to redissolve chromium carbides
C.Adding stabilizing elements like Ti or Nb to form stable carbides
D.Using low-carbon grades such as 304L or 316L
Correct Answer: Cold-working the steel after welding to increase dislocation density
Explanation:
Prevention targets chromium-carbide formation: use low-carbon grades, add carbide stabilizers (Ti, Nb), or solution-quench to redissolve carbides. Cold-working does not address the chromium depletion and cannot prevent sensitization.
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55A buried steel pipeline runs through alternating sandy and clay soils. Why is the section in clay more likely to become anodic and corrode?
Types of electrochemical corrosion-Intergranular and Soil corrosion
Hard
A.Soil type has no bearing; corrosion depends only on pipe metallurgy
B.Clay is denser and less aerated, so that section is oxygen-starved and anodic relative to the well-aerated sandy section
C.Sandy soil retains water and increases anodic dissolution in that zone
D.Clay holds more oxygen, making the pipe there strongly cathodic
Correct Answer: Clay is denser and less aerated, so that section is oxygen-starved and anodic relative to the well-aerated sandy section
Explanation:
Differential aeration between soil types creates a macro-cell. The compact, poorly aerated clay zone is oxygen-deficient (anode) while the porous sandy zone is oxygen-rich (cathode), concentrating attack on the clay section.
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56Regarding the effect of the anode-to-cathode area ratio on corrosion rate, which condition produces the most rapid, dangerous localized attack?
Types of electrochemical corrosion-Intergranular and Soil corrosion and Factors affecting corrosion
Hard
A.Large anode coupled to a small cathode, spreading current over a wide area
B.Equal anode and cathode areas, giving uniform low current density
C.Small anode coupled to a large cathode, concentrating a high current density on the small anode
D.No relation exists between area ratio and corrosion rate
Correct Answer: Small anode coupled to a large cathode, concentrating a high current density on the small anode
Explanation:
The total cathodic current must be balanced by the anodic current. A small anode with a large cathode forces a very high current density (corrosion rate) at the small anode, causing intense, rapid penetration.
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57In impressed current cathodic protection (ICCP) of a buried steel tank, the structure is connected to the negative terminal of a DC source with an inert anode. How does this differ fundamentally from sacrificial anode protection?
Protection of corrosion
Hard
A.ICCP uses an external power source and inert/semi-inert anodes, while sacrificial protection relies on a more active metal being consumed
B.ICCP consumes the steel structure, while sacrificial protection uses an external power source
C.Both methods make the protected metal anodic to suppress cathodic reactions
D.ICCP requires a more noble metal anode that is never consumed at all
Correct Answer: ICCP uses an external power source and inert/semi-inert anodes, while sacrificial protection relies on a more active metal being consumed
Explanation:
ICCP forces the structure cathodic using an impressed DC current with durable anodes (e.g., graphite, Pt-Ti), suited for long-term/large structures. Sacrificial protection uses an active metal (Zn, Mg) that corrodes preferentially and needs periodic replacement.
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58Anodic (passivation) inhibitors such as chromates and phosphates are described as "dangerous" inhibitors. Why can insufficient dosing be worse than adding none?
Protection of corrosion
Hard
A.Incomplete surface coverage leaves small unprotected anodes with a large cathode, causing intense localized pitting
B.Underdosing raises the pH so high that the metal dissolves as a complex
C.Low doses convert the whole surface into a uniform cathode, stopping all corrosion
D.They accelerate hydrogen evolution over the entire surface at any dose
Correct Answer: Incomplete surface coverage leaves small unprotected anodes with a large cathode, causing intense localized pitting
Explanation:
Anodic inhibitors passivate anodic sites. If dosing is inadequate, some anodes stay active while the large passivated area acts as cathode; the resulting small-anode/large-cathode geometry drives severe pitting.
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59Ceramic coatings (e.g., oxides, carbides, nitrides) protect metals in aggressive high-temperature environments. Which property mismatch is the most critical failure risk to control when applying a ceramic coating on a metal substrate?
Protection of corrosion-Ceramic coating
Hard
A.The high electrical conductivity of the ceramic, which promotes galvanic coupling
B.A large difference in thermal expansion coefficients, which causes cracking or spalling during thermal cycling
C.The low melting point of ceramics compared to the metal substrate
D.The ductility of ceramics being higher than that of the metal
Correct Answer: A large difference in thermal expansion coefficients, which causes cracking or spalling during thermal cycling
Explanation:
Ceramics are hard, chemically inert, and heat-resistant but brittle. A mismatch in thermal expansion between coating and substrate builds interfacial stress on heating/cooling, leading to cracking or spalling and loss of protection.
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60In an electroplating operation, a current of is passed for seconds through a copper sulphate bath. Using Faraday's laws (, atomic mass , ), what mass of copper is deposited?
Electroplating process
Hard
A.
B.
C.
D.
Correct Answer:
Explanation:
Charge . Moles of electrons . Moles of . Mass .
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