1Which of the following represents the basic structural unit of the silica sheet in silicate clays?
A.Silicon Octahedron
B.Silicon Tetrahedron
C.Aluminum Octahedron
D.Aluminum Tetrahedron
Correct Answer: Silicon Tetrahedron
Explanation:The fundamental building block of the silica sheet is the Silicon Tetrahedron (), where one silicon atom is surrounded by four oxygen atoms.
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2What is the ratio of tetrahedral to octahedral sheets in the crystal structure of Kaolinite?
A.2:1
B.1:1
C.2:2
D.2:1:1
Correct Answer: 1:1
Explanation:Kaolinite is a 1:1 type clay mineral, meaning its crystal unit consists of one tetrahedral silica sheet and one octahedral alumina sheet.
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3Which phenomenon is primarily responsible for the permanent negative charge in 2:1 silicate clays?
A.Protonation of hydroxyl groups
B.Dissociation of carboxyl groups
C.Isomorphous substitution
D.Broken edge bonds
Correct Answer: Isomorphous substitution
Explanation:Isomorphous substitution is the replacement of one ion by another of similar size but different charge (e.g., replacing ) during mineral formation, creating a permanent negative charge.
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4Which cation typically dominates the interlayer space of Illite, preventing expansion?
A.
B.
C.
D.
Correct Answer:
Explanation:Potassium () ions fit snugly into the hexagonal holes of the tetrahedral sheets in Illite, bonding the layers together and preventing expansion.
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5According to the Lyotropic series, which of the following cations is most strongly adsorbed by soil colloids?
A.
B.
C.
D.
Correct Answer:
Explanation:The strength of adsorption generally increases with valence and decreases with hydrated radius. The order is usually .
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6The Cation Exchange Capacity (CEC) of a soil is best defined as:
A.The total weight of clay in the soil
B.The total number of exchangeable anions a soil can hold
C.The sum of total exchangeable cations that a soil can adsorb
D.The percentage of aluminum saturation
Correct Answer: The sum of total exchangeable cations that a soil can adsorb
Explanation:CEC is the total capacity of a soil to hold exchangeable cations, typically expressed in .
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7Which clay mineral typically has the highest Cation Exchange Capacity (CEC)?
A.Kaolinite
B.Illite
C.Vermiculite
D.Chlorite
Correct Answer: Vermiculite
Explanation:Among silicate clays, Vermiculite typically has the highest CEC () due to high isomorphous substitution in the tetrahedral sheet.
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8What is the standard unit for expressing Cation Exchange Capacity (CEC) in the SI system?
A.meq/100g
B.cmol(+)/kg
C.ppm
D.mg/kg
Correct Answer: cmol(+)/kg
Explanation:The standard SI unit is centimoles of charge per kilogram ( or ). Note that .
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9The swelling and shrinking behavior of Montmorillonite (Smectite) is caused by:
A.Water entering the interlayer space
B.Expansion of individual atoms
C.Breakdown of the crystal lattice
D.Precipitation of salts
Correct Answer: Water entering the interlayer space
Explanation:Smectites have weak bonding between layers, allowing water molecules to enter the interlayer space, causing the lattice to expand.
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10Calculate the Base Saturation percentage if a soil has a CEC of and the sum of exchangeable basic cations () is .
A.25%
B.75%
C.133%
D.50%
Correct Answer: 75%
Explanation:Base Saturation .
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11In the silicon tetrahedron, the central silicon ion () is surrounded by how many oxygen ions?
A.3
B.4
C.6
D.8
Correct Answer: 4
Explanation:A tetrahedron is a four-sided pyramid shape where the central cation is coordinated with 4 oxygen ions.
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12Which source of charge is considered 'pH-dependent'?
A.Isomorphous substitution in the tetrahedral layer
B.Isomorphous substitution in the octahedral layer
C.Dissociation of hydroxyl (-OH) groups on broken edges
D.Substitution of for
Correct Answer: Dissociation of hydroxyl (-OH) groups on broken edges
Explanation:The dissociation of from -OH groups at broken crystal edges or in organic matter depends on the pH of the soil solution, making it a variable or pH-dependent charge.
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13Anion Exchange Capacity (AEC) generally increases when:
A.Soil pH increases
B.Soil pH decreases
C.Organic matter content increases
D.CEC increases
Correct Answer: Soil pH decreases
Explanation:AEC increases as pH decreases (becomes more acidic). Excess ions protonate surface hydroxyl groups (e.g., ), creating positive charges that attract anions.
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14Which of the following is considered an 'acidic cation' in the context of base saturation?
A.
B.
C.
D.
Correct Answer:
Explanation:Aluminum () and Hydrogen () are acidic cations. Base saturation is the percentage of CEC occupied by non-acidic (basic) cations.
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15Buffering capacity in soils refers to:
A.The ability to drain water rapidly
B.The resistance to change in soil pH
C.The maximum amount of fertilizer a soil can hold
D.The rate of organic matter decomposition
Correct Answer: The resistance to change in soil pH
Explanation:Buffering capacity is the soil's ability to resist changes in pH when acids or bases are added.
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16Active acidity in soil is defined as:
A. ions adsorbed on the clay complex
B. ions in the crystal lattice
C. ions present in the soil solution
D.Total acidity minus exchangeable acidity
Correct Answer: ions present in the soil solution
Explanation:Active acidity refers to the hydrogen ion activity () currently in the soil solution, which is measured by a pH meter.
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17Which soil component contributes most significantly to pH-dependent charge (variable charge)?
A.Sand particles
B.Soil Humus (Organic Matter)
C.Vermiculite
D.Smectite
Correct Answer: Soil Humus (Organic Matter)
Explanation:Humus has a very high CEC that is almost entirely pH-dependent, resulting from the dissociation of carboxylic (-COOH) and phenolic (-OH) groups.
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18Which equation correctly represents the stoichiometry of cation exchange?
A.
B.
C.
D.
Correct Answer:
Explanation:Cation exchange is stoichiometric (charge-for-charge). One divalent cation () is exchanged for two monovalent cations () to maintain charge balance.
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19In the aluminum octahedron, the coordination number of Aluminum is:
A.4
B.6
C.8
D.12
Correct Answer: 6
Explanation:In an octahedron, the central aluminum (or magnesium) cation is surrounded by 6 oxygen or hydroxyl ions.
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20Which of the following clay minerals is non-expanding?
A.Montmorillonite
B.Vermiculite
C.Kaolinite
D.Beidellite
Correct Answer: Kaolinite
Explanation:Kaolinite is a 1:1 clay where layers are held tightly by hydrogen bonding, preventing water entry and expansion.
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21The 'Point of Zero Charge' (PZC) is the pH at which:
A.The soil has no cations
B.The net surface charge of the colloid is zero
C.The CEC is at its maximum
D.The soil becomes highly alkaline
Correct Answer: The net surface charge of the colloid is zero
Explanation:The PZC is the pH value where the positive charges on the colloid surface exactly equal the negative charges, resulting in a net charge of zero.
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22Which mechanism creates a permanent charge in Montmorillonite?
A.Substitution of for in the octahedral sheet
B.Substitution of for in the tetrahedral sheet
C.Broken edges
D.Protonation
Correct Answer: Substitution of for in the octahedral sheet
Explanation:In Montmorillonite (a smectite), the primary source of charge is the isomorphous substitution of for in the octahedral sheet.
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23Reserve (or potential) acidity is typically _____ than active acidity.
A.Much lower
B.Exactly the same as
C.Much higher
D.Unrelated to
Correct Answer: Much higher
Explanation:Reserve acidity (ions adsorbed on colloids) is usually thousands of times higher than active acidity (ions in solution). This acts as the buffer reservoir.
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24If a soil has a high buffering capacity, adding lime will:
A.Raise the pH very quickly
B.Raise the pH slowly
C.Have no effect
D.Lower the pH
Correct Answer: Raise the pH slowly
Explanation:High buffering capacity means the soil resists pH change. Therefore, it requires more lime to affect a change, and the pH rises slowly compared to a poorly buffered soil.
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25Which colloid type is known as 'Amorphous' (non-crystalline)?
A.Kaolinite
B.Allophane
C.Illite
D.Montmorillonite
Correct Answer: Allophane
Explanation:Allophane and Imogolite are non-crystalline (amorphous) silicate clays typically found in volcanic ash soils (Andisols).
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26Which of the following is an oxide clay commonly found in highly weathered tropical soils?
A.Gibbsite
B.Smectite
C.Vermiculite
D.Mica
Correct Answer: Gibbsite
Explanation:Gibbsite () is an aluminum oxide mineral dominant in highly weathered soils (Oxisols/Ultisols).
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27The specific surface area is highest in which of the following clays?
A.Kaolinite
B.Illite
C.Montmorillonite
D.Fine sand
Correct Answer: Montmorillonite
Explanation:Montmorillonite has a very high specific surface area () because it has both external and extensive internal (interlayer) surface area.
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28The conversion factor between and is:
A.1:10
B.1:1
C.10:1
D.1:100
Correct Answer: 1:1
Explanation:The values are numerically identical. .
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29Dispersion of soil colloids is primarily promoted by which cation?
A.
B.
C.
D.
Correct Answer:
Explanation:Sodium () has a large hydrated radius and low valence, which increases the thickness of the diffuse double layer, causing particles to repel each other (disperse).
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30Flocculation is the process of:
A.Breaking down clay particles
B.Aggregating individual particles into clumps
C.Leaching cations from soil
D.Measuring soil pH
Correct Answer: Aggregating individual particles into clumps
Explanation:Flocculation is the coming together of colloidal particles to form small clumps or floccules, usually promoted by polyvalent cations like and .
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31Chlorite is structurally similar to vermiculite but contains an extra layer of:
A.Potassium ions
B.Water molecules
C.Magnesium-hydroxide (Brucite)
D.Silica tetrahedra
Correct Answer: Magnesium-hydroxide (Brucite)
Explanation:Chlorite is often called a 2:1:1 or 2:2 mineral because it has a brucite-like magnesium-hydroxide sheet occupying the interlayer space.
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32Which functional group is primarily responsible for the CEC of soil organic matter?
A.Amino groups ()
B.Carboxyl groups ()
C.Silanol groups ()
D.Aluminol groups ()
Correct Answer: Carboxyl groups ()
Explanation:The dissociation of from carboxyl groups (and phenolic groups) on humus colloids creates negative charges contributing to CEC.
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33In a 2:1 clay mineral, the '2' refers to:
A.Two octahedral sheets
B.Two tetrahedral sheets
C.Two interlayer spaces
D.Two types of cations
Correct Answer: Two tetrahedral sheets
Explanation:The designation 2:1 indicates the crystal structure has two tetrahedral sheets sandwiching one octahedral sheet.
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34A soil with a Base Saturation of 20% would likely have a pH that is:
A.Neutral (7.0)
B.Alkaline (> 7.0)
C.Acidic (< 5.5)
D.Variable
Correct Answer: Acidic (< 5.5)
Explanation:Low base saturation means the exchange sites are dominated by acidic cations (), resulting in an acidic pH.
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35Which law states that the ratio of cations on the exchange surface is proportional to the ratio of their activities in the soil solution?
A.Darcy's Law
B.Stoke's Law
C.Ratio Law
D.Beer's Law
Correct Answer: Ratio Law
Explanation:The Ratio Law describes the equilibrium relationship where the ratio of cations adsorbed matches the ratio in the bulk solution (adjusted for valence).
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36Why does Kaolinite have a much lower CEC than Smectite?
A.It has high isomorphous substitution
B.It has very little isomorphous substitution and low surface area
C.It contains potassium in the interlayer
D.It is an amorphous colloid
Correct Answer: It has very little isomorphous substitution and low surface area
Explanation:Kaolinite's charge comes mostly from broken edges (pH dependent) rather than isomorphous substitution, and its 1:1 structure limits surface area, resulting in low CEC ().
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37Which cation exchange reaction represents the process of acidification?
A.
B.
C.
D.
Correct Answer:
Explanation:Acidification involves ions replacing basic cations (like ) on the exchange complex.
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38The 'Oscillation Volume' refers to:
A.The volume of water a clay expands into
B.The space where adsorbed cations move around the colloid surface
C.The volume of air in soil pores
D.The shrinkage limit of soil
Correct Answer: The space where adsorbed cations move around the colloid surface
Explanation:Adsorbed cations are not fixed rigidly; they swarm around the colloid surface within a specific oscillation volume due to thermal motion and electrostatic attraction.
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39Which of the following creates a 'tetrahedral sheet'?
A.Linking of tetrahedra through sharing of basal oxygen atoms
B.Linking of octahedra through hydroxyl groups
C.Stacking of silica and alumina units
D.Hydration of silicon atoms
Correct Answer: Linking of tetrahedra through sharing of basal oxygen atoms
Explanation:Silicon tetrahedra link together by sharing the oxygen atoms at their bases, forming a continuous hexagonal sheet.
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40What is the primary process responsible for the release of ions from Aluminum () in soil solution?
A.Reduction
B.Hydrolysis
C.Oxidation
D.Chelation
Correct Answer: Hydrolysis
Explanation:Aluminum undergoes hydrolysis (reaction with water): . This releases protons, lowering pH.
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41Which soil texture typically has the lowest buffering capacity?
A.Clay Loam
B.Silty Clay
C.Sand
D.Peat (Organic Soil)
Correct Answer: Sand
Explanation:Sandy soils have low clay and organic matter content, meaning they have very low CEC and reserve acidity, resulting in poor buffering capacity.
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42Isomorphous substitution usually occurs during:
A.Weathering of existing minerals
B.Fertilizer application
C.The crystallization of clay minerals from molten magma or solution
D.Organic matter decomposition
Correct Answer: The crystallization of clay minerals from molten magma or solution
Explanation:Isomorphous substitution is a geologic event happening during the formation/crystallization of the mineral lattice, not a subsequent surface reaction.
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43If the concentration of in the soil solution increases, what happens to the adsorbed on the colloid?
A.It decreases
B.It increases
C.It remains unchanged
D.It turns into
Correct Answer: It increases
Explanation:According to the principles of mass action and equilibrium, increasing the concentration of a cation in solution forces more of that cation onto the exchange complex (increases adsorption).
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44The negative charge on humus is primarily:
A.Permanent
B.pH-Dependent
C.Positive
D.Neutral
Correct Answer: pH-Dependent
Explanation:Humus charge is derived principally from functional groups that dissociate as pH rises, making it pH-dependent.
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45Anions like Nitrate () and Chloride () are generally:
A.Strongly adsorbed by silicate clays
B.Repelled by the negative charge of silicate clays
C.Precipitated as solids immediately
D.Converted to cations
Correct Answer: Repelled by the negative charge of silicate clays
Explanation:Since silicate clays have a net negative charge, they repel negatively charged anions (anion exclusion), making these anions prone to leaching.
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46Which cation is most effective at causing soil particles to disperse, leading to poor structure?
A.
B.
C.
D.
Correct Answer:
Explanation:Sodium has a large hydrated radius and monovalent charge, preventing close approach of particles and causing dispersion.
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47A 2:1 clay with high lattice charge located in the tetrahedral sheet, limiting expansion, describes:
A.Kaolinite
B.Smectite
C.Vermiculite
D.Goethite
Correct Answer: Vermiculite
Explanation:Vermiculite has high substitution in the tetrahedral sheet ( for ), creating a strong negative charge that holds layers closer than smectite, allowing only limited expansion.
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48The 'Complementary Ion Effect' describes how:
A.Anions attract cations
B.The ease of replacing a specific ion depends on the strength of adsorption of other ions present
C.pH changes the color of the soil
D.Water molecules complement clay structures
Correct Answer: The ease of replacing a specific ion depends on the strength of adsorption of other ions present
Explanation:If a cation is surrounded by loosely held neighbors (complementary ions), it is harder to replace. If surrounded by tightly held neighbors, it is easier to replace.
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49Generally, the CEC of a soil usually ___ with an increase in soil organic matter.
A.Decreases
B.Increases
C.Stays the same
D.Fluctuates randomly
Correct Answer: Increases
Explanation:Since organic matter has a very high CEC (), adding it to soil generally increases the overall soil CEC.
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50When measuring soil pH with water, the result represents:
A.Potential Acidity
B.Total Acidity
C.Active Acidity
D.Exchangeable Acidity
Correct Answer: Active Acidity
Explanation:Measurement in water detects the ions currently free in the solution, which is the active acidity.
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