1Soil colloids are generally defined by particle sizes smaller than which of the following?
A.
B.
C.
D.
Correct Answer:
Explanation:Soil colloids are the most active portion of the soil and are defined as particles with a diameter less than (or ).
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2Which of the following is not a general property of soil colloids?
A.High surface area per unit mass
B.Surface electric charge
C.Adsorption of cations and water
D.Settles rapidly in water
Correct Answer: Settles rapidly in water
Explanation:Due to their small size and Brownian movement, soil colloids remain in suspension for long periods and do not settle rapidly compared to sand or silt.
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3The fundamental building block of silicate clays consisting of one silicon atom surrounded by four oxygen atoms is known as a:
A.Silicon Octahedron
B.Silicon Tetrahedron
C.Aluminum Octahedron
D.Magnesium Tetrahedron
Correct Answer: Silicon Tetrahedron
Explanation:The basic structural unit is a silica tetrahedron (), where one silicon ion is coordinated with four oxygen ions.
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4Which clay mineral typically has a 1:1 crystal structure?
A.Montmorillonite
B.Illite
C.Kaolinite
D.Vermiculite
Correct Answer: Kaolinite
Explanation:Kaolinite is a 1:1 clay mineral, meaning its crystal unit consists of one tetrahedral sheet and one octahedral sheet.
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5In a 2:1 type silicate clay, the structure consists of:
A.One tetrahedral sheet sandwiched between two octahedral sheets
B.One octahedral sheet sandwiched between two tetrahedral sheets
C.Alternating single sheets of silica and alumina
D.One octahedral sheet and one tetrahedral sheet only
Correct Answer: One octahedral sheet sandwiched between two tetrahedral sheets
Explanation:2:1 clays (like smectite and vermiculite) have a crystal lattice composed of one alumina/magnesia octahedral sheet sandwiched between two silica tetrahedral sheets.
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6Which phenomenon is primarily responsible for the permanent negative charge found in 2:1 silicate clays?
A.pH-dependent dissociation
B.Protonation of hydroxyl groups
C.Isomorphous substitution
D.Broken edges of crystal lattices
Correct Answer: Isomorphous substitution
Explanation:Isomorphous substitution is the replacement of one ion for another of similar size within the crystal lattice (e.g., for ) during mineral formation, resulting in a net permanent negative charge.
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7Which of the following clay minerals has the highest Cation Exchange Capacity (CEC)?
A.Kaolinite
B.Illite
C.Vermiculite
D.Gibbsite
Correct Answer: Vermiculite
Explanation:Vermiculite typically has the highest CEC (approx 100-150 ) among the silicate clays, often exceeding montmorillonite and significantly higher than kaolinite or illite.
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8Illite is a non-expanding 2:1 clay primarily because of the fixation of which ion in the interlayer space?
A.
B.
C.
D.
Correct Answer:
Explanation:Potassium ions () fit snugly into the hexagonal holes of the tetrahedral sheets in Illite, bonding the layers tightly together and preventing expansion.
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9Which group of soil colloids is amorphous (non-crystalline) and typically found in soils derived from volcanic ash?
A.Smectites
B.Allophane and Imogolite
C.Iron oxides
D.Micas
Correct Answer: Allophane and Imogolite
Explanation:Allophane and Imogolite are amorphous aluminosilicates (short-range order minerals) characteristically found in Andisols (volcanic ash soils).
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10What is the primary source of charge on humus (organic colloids)?
A.Isomorphous substitution
B.pH-dependent dissociation of functional groups
C.Interlayer fixation
D.Van der Waals forces
Correct Answer: pH-dependent dissociation of functional groups
Explanation:The charge on humus is almost entirely pH-dependent, arising from the dissociation of from functional groups like carboxyl () and phenolic () groups.
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11Under highly acidic conditions, the edges of Kaolinite may develop a positive charge due to:
A.Protonation
B.Deprotonation
C.Isomorphous substitution
D.Anion repulsion
Correct Answer: Protonation
Explanation:At low pH (high concentration), the hydroxyl groups at the broken edges of clay crystals can accept protons (), resulting in a net positive charge (protonation).
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12The Cation Exchange Capacity (CEC) is commonly expressed in which units?
A.
B.
C.
D.
Correct Answer:
Explanation:CEC is the total capacity of a soil to hold exchangeable cations and is expressed in centimoles of charge per kilogram of soil ().
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13Which of the following sequences represents the correct order of adsorption strength (Lyotropic series) for cations on clay surfaces?
A.
B.
C.
D.
Correct Answer:
Explanation:Cations with higher valence and smaller hydrated radius are held more tightly. The general order is .
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14The specific surface area of Montmorillonite (Smectite) is significantly higher than Kaolinite because:
A.It has only external surface area
B.It has both internal and external surface area
C.It is a 1:1 clay
D.It contains potassium bridges
Correct Answer: It has both internal and external surface area
Explanation:Smectites expand, allowing water and ions to enter the interlayer spaces. This provides a massive internal surface area in addition to the external surface, unlike non-expanding kaolinite.
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15Which organic matter fraction is soluble in alkali but precipitates when the solution is acidified?
A.Fulvic acid
B.Humic acid
C.Humin
D.Lignin
Correct Answer: Humic acid
Explanation:Humic acid is the fraction of humic substances that is soluble in alkaline solution but insoluble (precipitates) in acid solution.
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16The 'Van Bemmelen factor' used to estimate Soil Organic Matter (SOM) from Soil Organic Carbon (SOC) is approximately:
A.1.724
B.0.58
C.2.50
D.1.00
Correct Answer: 1.724
Explanation:It is traditionally assumed that SOM contains approximately 58% carbon. Therefore, .
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17A soil C:N ratio of 50:1 would likely result in which process?
A.Net Mineralization of Nitrogen
B.Net Immobilization of Nitrogen
C.Immediate release of Nitrate
D.No biological activity
Correct Answer: Net Immobilization of Nitrogen
Explanation:When C:N is wide (), microbes consume available soil nitrogen to process the carbon, leading to net immobilization (N becomes unavailable to plants).
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18Which component of plant residues is most resistant to decomposition?
A.Sugars
B.Proteins
C.Cellulose
D.Lignin
Correct Answer: Lignin
Explanation:Lignin is a complex aromatic polymer that is very resistant to microbial degradation, persisting in the soil longer than sugars, proteins, or cellulose.
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19The process by which individual clay particles stick together to form flake-like aggregates is called:
A.Dispersion
B.Flocculation
C.Cementation
D.Leaching
Correct Answer: Flocculation
Explanation:Flocculation is the aggregation of colloidal particles into clusters or flocs, often promoted by polyvalent cations like and .
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20Which cation is the most effective dispersing agent, often leading to poor soil structure?
A.
B.
C.
D.
Correct Answer:
Explanation:Sodium () has a large hydrated radius and low charge, causing colloids to repel each other (dispersion), which breaks down soil structure.
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21Sesquioxides are soil colloids dominated by:
A.Silicon and Oxygen
B.Iron and Aluminum oxides
C.Potassium and Magnesium
D.Calcium carbonate
Correct Answer: Iron and Aluminum oxides
Explanation:Sesquioxides refer to oxides and hydroxides of iron and aluminum (e.g., Gibbsite, Goethite), common in highly weathered soils.
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22Chlorite is structurally similar to vermiculite but contains an additional sheet in the interlayer space composed of:
Explanation:Chlorite is essentially a 2:1:1 mineral, having a 2:1 layer plus a brucite-like (-hydroxide) sheet in the interlayer.
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23The Point of Zero Charge (PZC) is the pH at which:
A.The soil has no cations
B.The net surface charge of the colloid is zero
C.The soil pH is 7.0
D.The CEC is maximum
Correct Answer: The net surface charge of the colloid is zero
Explanation:The PZC is the specific pH value where the positive charges on variable charge surfaces exactly balance the negative charges, resulting in a net zero charge.
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24Which fraction of humic substances is soluble in both acid and alkali?
A.Humin
B.Humic acid
C.Fulvic acid
D.Hematite
Correct Answer: Fulvic acid
Explanation:Fulvic acid has a lower molecular weight and higher oxygen content than humic acid and is soluble in water across the entire pH range (acid and alkali).
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25In the octahedral sheet of silicate clays, the central cation is typically:
A. or
B. or
C. or
D. or
Correct Answer: or
Explanation:Octahedral sheets are composed of atoms (usually or ) coordinated with six oxygen/hydroxyl groups.
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26Which of the following is true regarding the swelling/shrinking capacity of Kaolinite?
A.Very high expansion upon wetting
B.Moderate expansion
C.Little to no expansion
D.Expands only in acid soils
Correct Answer: Little to no expansion
Explanation:Kaolinite is a 1:1 non-expanding clay. Hydrogen bonding between layers prevents water from entering the interlayer space.
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27The breakdown of organic nitrogen compounds into ammonium () is specifically called:
A.Nitrification
B.Denitrification
C.Aminization and Ammonification
D.Immobilization
Correct Answer: Aminization and Ammonification
Explanation:Mineralization of N involves enzymatic hydrolysis of proteins to amines (aminization) and then to ammonium (ammonification).
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28Which soil colloid typically exhibits the highest specific surface area?
A.Kaolinite
B.Illite
C.Humus
D.Fine Sand
Correct Answer: Humus
Explanation:Humus is highly colloidal and generally has a specific surface area and CEC greater than silicate clays, including montmorillonite.
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29Anion Exchange Capacity (AEC) is most likely to be significant in:
A.Alkaline soils with 2:1 clays
B.Highly weathered, acidic soils rich in Fe/Al oxides
C.Soils high in organic matter only
D.Saline soils
Correct Answer: Highly weathered, acidic soils rich in Fe/Al oxides
Explanation:AEC increases as pH drops. Oxides of Fe and Al develop net positive charges at low pH, attracting anions.
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30The ratio of Silicon to Oxygen in a silica tetrahedron is:
A.1:2
B.1:4
C.2:1
D.1:6
Correct Answer: 1:4
Explanation:A single tetrahedron consists of one Silicon atom and four Oxygen atoms (). Note: in sheet structures, oxygen sharing alters the empirical formula.
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31Which of the following is a crystalline Iron oxide mineral?
A.Goethite
B.Gibbsite
C.Kaolinite
D.Quartz
Correct Answer: Goethite
Explanation:Goethite () is a common crystalline iron oxide mineral in soils. Gibbsite is an aluminum oxide.
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32The term 'isomorphous substitution' in tetrahedrons usually involves the substitution of:
A. for
B. for
C. for
D. for
Correct Answer: for
Explanation:In the tetrahedral sheet, (radius 0.039 nm) can substitute for (radius 0.042 nm), creating a charge imbalance.
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33Which of the following represents the correct C:N ratio range where neither net mineralization nor net immobilization occurs (equilibrium)?
A.10:1 to 15:1
B.20:1 to 30:1
C.40:1 to 50:1
D.> 80:1
Correct Answer: 20:1 to 30:1
Explanation:The transition zone is typically between 20:1 and 30:1. Below 20:1, mineralization dominates; above 30:1, immobilization dominates.
Correct Answer: Promoting aggregation and structure stability
Explanation:Humus acts as a cementing agent, binding soil particles into stable aggregates, which improves aeration, infiltration, and structure.
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35The bonding force holding layers of Montmorillonite together is:
A.Strong Hydrogen bonds
B.Potassium bridges
C.Weak Van der Waals forces
D.Covalent bonds
Correct Answer: Weak Van der Waals forces
Explanation:The layers in montmorillonite are held loosely by weak oxygen-to-oxygen linkages and Van der Waals forces, allowing water to enter easily.
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36Which term describes the process where metal ions are bonded to organic molecules forming a ring structure, increasing metal solubility or availability?
A.Precipitation
B.Chelation
C.Flocculation
D.Volatilization
Correct Answer: Chelation
Explanation:Chelation involves organic molecules (chelates) bonding to a central metal ion (like , , ) at two or more points, often keeping the metal soluble.
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37Base Saturation is defined as:
A.The percentage of CEC occupied by basic cations ()
B.The percentage of CEC occupied by acidic cations ()
C.The total amount of cations in the soil solution
D.The saturation of soil pores with water
Correct Answer: The percentage of CEC occupied by basic cations ()
Explanation:Base Saturation = (Sum of basic cations / Total CEC) 100.
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38The 'Diffuse Double Layer' theory explains:
A.The formation of humus
B.The distribution of ions near a charged colloid surface
C.The weathering of feldspar
D.The decomposition of lignin
Correct Answer: The distribution of ions near a charged colloid surface
Explanation:The theory describes how a 'cloud' of counter-ions (cations) surrounds a negatively charged colloid particle in solution, with concentration decreasing with distance.
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39Gibbsite is an example of:
A.Iron oxide
B.Aluminum hydroxide
C.Silicate clay
D.Organic colloid
Correct Answer: Aluminum hydroxide
Explanation:Gibbsite is a mineral composed of aluminum hydroxide, , and is common in highly weathered soils.
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40Which of the following organic compounds decomposes most rapidly in soil?
A.Lignin
B.Cellulose
C.Simple sugars and starches
D.Waxes
Correct Answer: Simple sugars and starches
Explanation:Simple carbohydrates like sugars and starches are easily utilized by microorganisms and decompose very rapidly.
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41The interlayer spacing (c-spacing) of expanded Montmorillonite with water can reach up to:
A.0.7 nm
B.1.0 nm
C.1.4 nm to > 2.0 nm
D.0.1 nm
Correct Answer: 1.4 nm to > 2.0 nm
Explanation:While collapsed it is near 1.0 nm, upon wetting, montmorillonite can expand significantly, often exceeding 2.0 nm depending on the cation and hydration.
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42Which clay mineral is most commonly associated with 'cracking' soils (Vertisols)?
A.Kaolinite
B.Smectite/Montmorillonite
C.Chlorite
D.Illite
Correct Answer: Smectite/Montmorillonite
Explanation:Due to its high shrink-swell capacity, smectite causes deep cracks in dry seasons and swelling in wet seasons, characteristic of Vertisols.
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43In the context of soil organic matter, 'Active Carbon' refers to:
A.The very old, stable humus
B.The fraction easily utilized by microbes (labile)
C.Charcoal
D.Carbonate minerals
Correct Answer: The fraction easily utilized by microbes (labile)
Explanation:Active carbon is the labile fraction of SOM that serves as a readily available food source for soil microbes.
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44What is the primary effect of high sodium saturation on soil colloids?
A.Increased flocculation
B.Dispersion and puddling
C.Increased aeration
D.Formation of stable aggregates
Correct Answer: Dispersion and puddling
Explanation:High sodium creates a large hydrated radius and zeta potential that repels particles, causing dispersion, sealing pores, and leading to puddling/poor drainage.
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45The net charge of 1:1 clays like Kaolinite is primarily:
A.High permanent negative charge
B.Low pH-dependent charge
C.High permanent positive charge
D.Zero under all conditions
Correct Answer: Low pH-dependent charge
Explanation:Kaolinite has very little isomorphous substitution. Its charge is low and arises mostly from broken edges (pH-dependent).
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46Vermiculite differs primarily from smectite by having:
A.Lower CEC
B.Higher negative charge in the tetrahedral sheet
C.No isomorphous substitution
D.A 1:1 structure
Correct Answer: Higher negative charge in the tetrahedral sheet
Explanation:Vermiculite has significant substitution of for in the tetrahedral sheet, creating a higher charge density than smectite, which holds interlayer cations more tightly (limited expansion).
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47Which functional group is most responsible for the acidity of soil organic matter?
A.Amino ()
B.Carboxyl ()
C.Methyl ()
D.Aldehyde ()
Correct Answer: Carboxyl ()
Explanation:Carboxyl groups dissociate easily (), contributing significantly to the negative charge and acidity of SOM.
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48Colloidal particles in suspension exhibiting random, rapid zigzag motion is a phenomenon known as:
A.Tyndall effect
B.Brownian movement
C.Osmosis
D.Diffusion
Correct Answer: Brownian movement
Explanation:Brownian movement is the random motion of particles suspended in a medium, resulting from collisions with the fast-moving molecules in the fluid.
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49The total surface area of a soil is dominated by:
A.The sand fraction
B.The silt fraction
C.The colloidal fraction (clay + humus)
D.The gravel fraction
Correct Answer: The colloidal fraction (clay + humus)
Explanation:Due to the inverse relationship between particle size and surface area, the colloidal fraction contributes the vast majority of the soil's specific surface area.
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50In the weathering sequence of clay minerals, which is considered the most weathered (end product)?
A.Illite
B.Vermiculite
C.Smectite
D.Sesquioxides (Fe/Al oxides)
Correct Answer: Sesquioxides (Fe/Al oxides)
Explanation:As weathering progresses, silica is leached out. The sequence generally goes: Primary minerals 2:1 clays 1:1 clays Fe/Al Oxides (Sesquioxides).
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