1Which phenomenon could not be explained by classical mechanics, leading to the development of quantum mechanics?
A.Interference of light
B.Diffraction of light
C.Black body radiation spectrum
D.Polarization of light
Correct Answer: Black body radiation spectrum
Explanation:Classical mechanics failed to explain the spectral distribution of black body radiation, specifically leading to the 'Ultraviolet Catastrophe' at short wavelengths.
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2According to Planck's quantum theory, energy is emitted or absorbed in discrete packets called quanta. What is the energy of a single quantum of frequency ?
A.
B.
C.
D.
Correct Answer:
Explanation:Planck proposed that energy is quantized and given by , where is Planck's constant.
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3In the context of Black Body radiation, Wien's displacement law states that the product of wavelength corresponding to maximum intensity () and absolute temperature () is:
A.Zero
B.Infinity
C.A constant
D.Variable depending on the material
Correct Answer: A constant
Explanation:Wien's displacement law is expressed as , where is Wien's constant.
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4Which law of black body radiation successfully explains the energy distribution at longer wavelengths but fails at shorter wavelengths?
A.Wien's Law
B.Rayleigh-Jeans Law
C.Planck's Law
D.Stefan's Law
Correct Answer: Rayleigh-Jeans Law
Explanation:The Rayleigh-Jeans law works well for low frequencies (long wavelengths) but predicts infinite energy at high frequencies (short wavelengths), known as the ultraviolet catastrophe.
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5In the photoelectric effect, the minimum frequency of incident radiation required to eject an electron from a metal surface is called:
A.Stopping frequency
B.Threshold frequency
C.Kinetic frequency
D.Resonant frequency
Correct Answer: Threshold frequency
Explanation:The threshold frequency () is the minimum frequency below which no photo-emission occurs, regardless of the intensity of light.
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6Einstein's photoelectric equation is given by which of the following? (Where is max kinetic energy, is incident energy, and is work function)
A.
B.
C.
D.
Correct Answer:
Explanation:The maximum kinetic energy of the emitted electron is the difference between the incident photon energy and the work function of the metal.
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7Who proposed the concept of matter waves, stating that moving particles exhibit wave-like properties?
A.Werner Heisenberg
B.Erwin Schrodinger
C.Louis de Broglie
D.Max Planck
Correct Answer: Louis de Broglie
Explanation:Louis de Broglie hypothesized that material particles in motion display wave characteristics.
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8The de Broglie wavelength of a particle with momentum is given by:
A.
B.
C.
D.
Correct Answer:
Explanation:The de Broglie relationship connects wavelength and momentum as or .
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9If the kinetic energy of a non-relativistic particle of mass is doubled, how does its de Broglie wavelength change?
A.It becomes times the original.
B.It becomes times the original.
C.It becomes half the original.
D.It remains unchanged.
Correct Answer: It becomes times the original.
Explanation:Since , if becomes , becomes of the initial value.
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10What is the de Broglie wavelength of an electron accelerated through a potential difference of volts? (Approximate formula)
A. nm
B.
C.
D.
Correct Answer:
Explanation:Substituting the constants for an electron into , we get Angstroms.
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11For thermal neutrons at temperature , the de Broglie wavelength is proportional to:
A.
B.
C.
D.
Correct Answer:
Explanation:The wavelength is given by , so .
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12The velocity with which the phase of a wave travels is known as:
A.Group velocity
B.Phase velocity
C.Particle velocity
D.Drift velocity
Correct Answer: Phase velocity
Explanation:Phase velocity () describes the rate at which the phase of the wave propagates in space.
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13Group velocity () is defined mathematically as:
A.
B.
C.
D.
Correct Answer:
Explanation:Group velocity represents the velocity of the wave packet (envelope) and is given by the derivative of angular frequency with respect to the wave number.
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14For a non-relativistic material particle, the group velocity of the matter wave is equal to:
A.The phase velocity
B.The velocity of light
C.The particle velocity
D.Zero
Correct Answer: The particle velocity
Explanation:The group velocity of the matter wave associated with a particle is equal to the classical velocity of the particle itself.
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15In a non-dispersive medium, the relationship between phase velocity () and group velocity () is:
A.
B.
C.
D.
Correct Answer:
Explanation:In a non-dispersive medium, the phase velocity is independent of frequency, making the group velocity equal to the phase velocity.
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16The Heisenberg Uncertainty Principle states that it is impossible to simultaneously determine with arbitrary precision which pair of variables?
A.Energy and Velocity
B.Position and Momentum
C.Charge and Mass
D.Position and Time
Correct Answer: Position and Momentum
Explanation:Heisenberg's principle states , meaning position and momentum cannot both be measured precisely at the same time.
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17The mathematical form of the Heisenberg Uncertainty Principle for position () and momentum () is:
A.
B.
C.
D.
Correct Answer:
Explanation:The product of uncertainties is at least half the reduced Planck's constant ().
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18Using the Uncertainty Principle, which of the following can be explained?
A.Photoelectric effect
B.Non-existence of electrons in the nucleus
C.Black body radiation
D.Compton effect
Correct Answer: Non-existence of electrons in the nucleus
Explanation:If an electron were confined to the nucleus (very small ), the uncertainty in velocity would exceed the speed of light, which is physically impossible.
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19The uncertainty principle relating energy () and time () is given by:
A.
B.
C.
D.
Correct Answer:
Explanation:Energy and time form a conjugate pair similar to position and momentum.
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20Why is the Heisenberg uncertainty principle not observed in macroscopic objects?
A.Planck's constant is too large.
B.Planck's constant is extremely small relative to macroscopic scales.
C.Macroscopic objects do not move.
D.Macroscopic objects have no wave nature.
Correct Answer: Planck's constant is extremely small relative to macroscopic scales.
Explanation:Since is very small ( Js), the uncertainty is negligible for heavy macroscopic objects.
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21A wave function in quantum mechanics represents:
A.The exact path of a particle
B.The probability amplitude of a particle
C.The energy density of a particle
D.The charge density of a particle
Correct Answer: The probability amplitude of a particle
Explanation:The wave function is a complex quantity representing the probability amplitude of finding a particle in a given state.
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22According to Max Born's interpretation, the quantity represents:
A.Electric charge
B.Momentum density
C.Position probability density
D.Energy density
Correct Answer: Position probability density
Explanation: represents the probability of finding the particle per unit volume (probability density).
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23For a wave function to be physically acceptable, it must satisfy which of the following conditions?
A.It must be discontinuous.
B.It must be infinite at some points.
C.It must be single-valued and continuous.
D.It must have multiple values at a single point.
Correct Answer: It must be single-valued and continuous.
Explanation:A well-behaved wave function must be finite, continuous, and single-valued everywhere to ensure physical probability predictions.
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24The condition is known as the:
A.Orthogonality condition
B.Normalization condition
C.Uncertainty condition
D.Continuity condition
Correct Answer: Normalization condition
Explanation:The total probability of finding the particle somewhere in the universe must be 1 (100%).
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25The Schrodinger Time-Independent Wave Equation for a particle of mass moving in potential is:
A.
B.
C.
D.
Correct Answer:
Explanation:This is the standard form derived from the total energy equation , rearranging terms involving the Laplacian operator.
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26In the Schrodinger wave equation, the operator for momentum is:
A.
B.
C.
D.
Correct Answer:
Explanation:The quantum mechanical operator for momentum in one dimension is .
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27The Hamiltonian operator in Schrodinger's equation corresponds to which physical quantity?
A.Momentum
B.Total Energy
C.Kinetic Energy
D.Potential Energy
Correct Answer: Total Energy
Explanation:The Hamiltonian operator represents the total energy (Kinetic + Potential) of the system.
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28For a particle in a 1D rigid box of length , the potential energy inside the box () is:
A.
B.$1$
C.$0$
D.
Correct Answer: $0$
Explanation:Inside a free-particle box, the particle experiences no forces, so the potential energy is zero.
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29For a particle in a 1D rigid box of length , the potential energy outside the box is:
A.$0$
B.Finite constant
C.
D.Negative
Correct Answer:
Explanation:The walls are rigid and impenetrable, implied by an infinite potential barrier outside the box.
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30The allowed energy levels for a particle of mass in a 1D box of width are given by:
A.
B.
C.
D.
Correct Answer:
Explanation:This is the eigenvalue solution for the infinite potential well, where is an integer.
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31In the particle in a box problem, the integer is called the:
A.Refractive index
B.Quantum number
C.Phase constant
D.Decay constant
Correct Answer: Quantum number
Explanation: characterizes the discrete energy states and wave functions of the system.
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32What is the lowest possible energy (Zero Point Energy) for a particle in a 1D box?
A.
B.
C.
D.
Correct Answer:
Explanation:For (lowest state), . It cannot be zero due to the uncertainty principle.
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33The wave function for a particle in a 1D box of length is proportional to:
A.
B.
C.
D.
Correct Answer:
Explanation:The solution must be zero at the boundaries ( and ), which is satisfied by the sine function.
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34For a particle in a box, as the size of the box increases, the spacing between energy levels:
A.Increases
B.Decreases
C.Remains constant
D.Becomes zero immediately
Correct Answer: Decreases
Explanation:Energy is inversely proportional to . As increases, the energy levels get closer together (approaching a continuum).
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35What is the probability of finding the particle at the walls of a rigid box?
A.1
B.0.5
C.
D.Infinite
Correct Answer:
Explanation:The wave function is zero at the boundaries (walls) due to infinite potential, so probability is zero.
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36For the ground state () of a particle in a box of length , the probability of finding the particle is maximum at:
A.
B.
C.
D.
Correct Answer:
Explanation:The ground state wave function is a half sine wave, which peaks exactly in the middle of the box.
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37The energy of the second excited state for a particle in a box corresponds to which value of ?
A.n = 1
B.n = 2
C.n = 3
D.n = 4
Correct Answer: n = 3
Explanation:Ground state is , first excited is , second excited state is .
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38If the phase velocity of a matter wave is and the particle velocity is , then:
A.
B.
C.
D.
Correct Answer:
Explanation:Relativistically, phase velocity . Since , .
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39Which of the following equations represents the Schrodinger Time-Dependent equation?
A.
B.
C.
D.
Correct Answer:
Explanation:This is the general form governing the time evolution of the quantum state.
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40In the normalization constant for a particle in a box, the unit of the wave function in 1D is:
A.
B.
C.
D.No units
Correct Answer:
Explanation:Since , the unit of is length, so is length.
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41Which experiment verified the wave nature of electrons?
A.Michelson-Morley Experiment
B.Davisson-Germer Experiment
C.Rutherford Scattering
D.Millikan's Oil Drop Experiment
Correct Answer: Davisson-Germer Experiment
Explanation:Davisson and Germer observed diffraction patterns of electrons scattered by a nickel crystal, confirming de Broglie's hypothesis.
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42For a particle in a box, the number of nodes (points of zero probability inside the box) for the -th state is:
A.
B.
C.
D.
Correct Answer:
Explanation:The ground state () has 0 nodes, has 1 node. In general, there are nodes.
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43The phase velocity of de Broglie waves associated with a moving particle is always:
A.Equal to the speed of light
B.Less than the speed of light
C.Greater than the speed of light
D.Zero
Correct Answer: Greater than the speed of light
Explanation:. Since particle velocity , must be greater than . (Note: Information cannot travel at this speed, only the phase).
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44The operator for Kinetic Energy in Quantum Mechanics is:
A.
B.
C.
D.
Correct Answer:
Explanation:Kinetic energy . Replacing with , we get .
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45If the uncertainty in the position of a particle is zero, the uncertainty in its momentum is:
A.Zero
B.Finite
C.Infinite
D.
Correct Answer: Infinite
Explanation:From , if , then .
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46Which of the following is NOT a property of the wave function ?
A.It can be a complex number.
B.It must be quadratically integrable.
C.It represents the physical trajectory of the particle.
D.It contains all information about the system.
Correct Answer: It represents the physical trajectory of the particle.
Explanation:In QM, particles do not have defined trajectories like in classical mechanics. represents probability amplitudes.
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47The concept of 'Wave Packet' is introduced to resolve the issue that:
A.Phase velocity is greater than light velocity.
B.Group velocity is zero.
C.Waves cannot transport energy.
D.Particles have no mass.
Correct Answer: Phase velocity is greater than light velocity.
Explanation:A single wave has and infinite extent. A wave packet (superposition of waves) travels at and is localized, representing the particle physically.
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48Two particles have the same de Broglie wavelength. They must have the same:
A.Mass
B.Velocity
C.Momentum
D.Kinetic Energy
Correct Answer: Momentum
Explanation:Since , if is the same, momentum must be the same.
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49The energy difference between consecutive energy levels of a particle in a box depends on as:
A.
B.
C.
D.
Correct Answer:
Explanation:. The difference is proportional to .
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50If a proton and an electron have the same kinetic energy, which has the shorter wavelength?
A.Electron
B.Proton
C.Both have the same wavelength
D.Depends on the charge
Correct Answer: Proton
Explanation:. Since is same, . Proton mass is much larger than electron mass, so proton wavelength is shorter.
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